Abstract
This review covers literature on non-stabilized functionalized organolithium compounds since 1997. In this overview, we consider intermediates with different separation between the functional group and the carbonlithium bond (dn-reagents) and having different hybridization at the carbanionic centre. Special emphasis is given to the synthetic applications of these intermediates in order to prepare polyfunctionalized molecules.
Keywords: Organolithium Compounds, polyfunctionalized molecules
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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