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Current Organic Synthesis

Editor-in-Chief

ISSN (Print): 1570-1794
ISSN (Online): 1875-6271

Asymmetric Epoxidation of Electron-Deficient Olefins

Author(s): David Diez, Marta G. Nunez, Ana B. Anton, P. Garcia, R. .F. Moro, N. M. Garrido, Isidro S. Marcos, P. Basabe and Julio G. Urones

Volume 5, Issue 3, 2008

Page: [186 - 216] Pages: 31

DOI: 10.2174/157017908785133429

Price: $65

Abstract

This paper focuses on the latest developments in asymmetric epoxidation of electron-deficient olefins since the review by Porter and Skidmore on chiral ligand-metal peroxide systems, polyamino acid catalysed and organocatalysed epoxidations. Particular attention has been paid to the most recent advances using chiral pyrrolidines as organocatalysts.

Keywords: Asymmetric epoxidation, electron deficient olefins, organocatalysis, dioxiranes, chiral ligand, , metal peroxide systems, Juliá Colonna epoxidation

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