Abstract
This paper focuses on the latest developments in asymmetric epoxidation of electron-deficient olefins since the review by Porter and Skidmore on chiral ligand-metal peroxide systems, polyamino acid catalysed and organocatalysed epoxidations. Particular attention has been paid to the most recent advances using chiral pyrrolidines as organocatalysts.
Keywords: Asymmetric epoxidation, electron deficient olefins, organocatalysis, dioxiranes, chiral ligand, –, metal peroxide systems, Juliá Colonna epoxidation
Current Organic Synthesis
Title: Asymmetric Epoxidation of Electron-Deficient Olefins
Volume: 5 Issue: 3
Author(s): David Diez, Marta G. Nunez, Ana B. Anton, P. Garcia, R. .F. Moro, N. M. Garrido, Isidro S. Marcos, P. Basabe and Julio G. Urones
Affiliation:
Keywords: Asymmetric epoxidation, electron deficient olefins, organocatalysis, dioxiranes, chiral ligand, –, metal peroxide systems, Juliá Colonna epoxidation
Abstract: This paper focuses on the latest developments in asymmetric epoxidation of electron-deficient olefins since the review by Porter and Skidmore on chiral ligand-metal peroxide systems, polyamino acid catalysed and organocatalysed epoxidations. Particular attention has been paid to the most recent advances using chiral pyrrolidines as organocatalysts.
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Cite this article as:
Diez David, Nunez G. Marta, Anton B. Ana, Garcia P., Moro .F. R., Garrido M. N., Marcos S. Isidro, Basabe P. and Urones G. Julio, Asymmetric Epoxidation of Electron-Deficient Olefins, Current Organic Synthesis 2008; 5 (3) . https://dx.doi.org/10.2174/157017908785133429
DOI https://dx.doi.org/10.2174/157017908785133429 |
Print ISSN 1570-1794 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6271 |
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