Abstract
The synthesis and characterization of the first rigid fused porphyrin-phthalocyanine hetero-dyad with two different metals is reported; was based on porphyrin’s dienophile features in Diels–Alder reactions. This synthetic procedure represents a new approach for the synthesis of extended systems based on tetrapyrrolic macrocycles.
Keywords: Bimetallic systems, Diels-Alder reactions, Extended heterocyclic systems, Porphyrins, Phthalocyanines.
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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