Abstract
Organosilicon compounds are important transmetallation reagents in organic synthesis. Aryltrialkoxysilane have recently emerged as an attractive alternative to traditional organometallic donors, due to their ease of handling, stability toward air/moisture, and/or low toxicity compared to some of the other organometallic reagents (Zn, Mg, Sn, etc.). In this review, the application of aryl trialkoxysilane and alkenyltrialkoxysilane as transmetallation reagent for C-C, C-N, C-S and C-O bonds formation will be disclosed.
Keywords: Organosilicon, transmetallation reagent, organic synthesis, organostannanes, Hiyama Reaction, arylsiloxane, -substituted ketones, aldehydes, esters, nitriles, nitroalkanes, enamide derivatives, trialkoxysilane, trialkoxysilanes
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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