Abstract
Halogen dance (HD) reaction is an important tool in modern organic chemistry. This reaction is defined as halogen migration induced by bases, normally in aromatic and heteroaromatic systems. It is successfully applied in aromatic and different classes of heteroaromatic compounds, such as thiophene, quinoline, pyridine, thiazole, and many others. Due to the importance of this reaction, the aim of this review is to discuss the HD reaction and its application in organic synthesis between 1992-2005.
Keywords: Directed ortho-metalation, Oligothiophenes, Boc-protected aminoaldehyde, Periolidine, Cryptomisrine
Current Organic Chemistry
Title: Halogen Dance Reaction and its Application in Organic Synthesis
Volume: 11 Issue: 7
Author(s): Marcus Vinicius Nora de Souza
Affiliation:
Keywords: Directed ortho-metalation, Oligothiophenes, Boc-protected aminoaldehyde, Periolidine, Cryptomisrine
Abstract: Halogen dance (HD) reaction is an important tool in modern organic chemistry. This reaction is defined as halogen migration induced by bases, normally in aromatic and heteroaromatic systems. It is successfully applied in aromatic and different classes of heteroaromatic compounds, such as thiophene, quinoline, pyridine, thiazole, and many others. Due to the importance of this reaction, the aim of this review is to discuss the HD reaction and its application in organic synthesis between 1992-2005.
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Cite this article as:
Vinicius Nora de Souza Marcus, Halogen Dance Reaction and its Application in Organic Synthesis, Current Organic Chemistry 2007; 11 (7) . https://dx.doi.org/10.2174/138527207780598846
DOI https://dx.doi.org/10.2174/138527207780598846 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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