Abstract
Diacetyl-L-tartaric acid anhydride reacted with aromatic primary amines to yield imides (3g-l) and amides (4a-f). The ortho-substituted aromatic primary amines either with electron donating or withdrawing groups yielded amides, whereas para-substituted amines produced imides. However, meta-substituted aromatic primary amines with electron withdrawing residues afforded amides while electron donating counterparts furnished imides.
Keywords: Diacetyl-L-tartaric acid anhydride, aromatic primary amines, imides, amides
Letters in Organic Chemistry
Title: Synthesis of Imides and Amides from Diacetyl-L-Tartaric Acid Anhydride
Volume: 7 Issue: 4
Author(s): Sara Naz, Javid H. Zaidi, Tahir Mehmood, Sher Wali, Muhammad Ali, Muhammad Taha and Khalid M. Khan
Affiliation:
Keywords: Diacetyl-L-tartaric acid anhydride, aromatic primary amines, imides, amides
Abstract: Diacetyl-L-tartaric acid anhydride reacted with aromatic primary amines to yield imides (3g-l) and amides (4a-f). The ortho-substituted aromatic primary amines either with electron donating or withdrawing groups yielded amides, whereas para-substituted amines produced imides. However, meta-substituted aromatic primary amines with electron withdrawing residues afforded amides while electron donating counterparts furnished imides.
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Cite this article as:
Naz Sara, H. Zaidi Javid, Mehmood Tahir, Wali Sher, Ali Muhammad, Taha Muhammad and M. Khan Khalid, Synthesis of Imides and Amides from Diacetyl-L-Tartaric Acid Anhydride, Letters in Organic Chemistry 2010; 7 (4) . https://dx.doi.org/10.2174/157017810791130649
DOI https://dx.doi.org/10.2174/157017810791130649 |
Print ISSN 1570-1786 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6255 |
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