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Current Organic Chemistry

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ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

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Mini-Review Article

A Review on Piezoelectric-mediated Mechanoredox Reactions by Ball Milling in Organic Synthesis

Author(s): Shan Jiang and Miao Wang*

Volume 28, Issue 12, 2024

Published on: 03 May, 2024

Page: [905 - 913] Pages: 9

DOI: 10.2174/0113852728306541240409034052

Price: $65

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Abstract

Recently, the concept of mechanoredox chemistry has been proposed and welldeveloped in organic synthesis. Mechanoredox chemistry is conceptually similar to a photocatalyst reaction system, where piezoelectric materials are introduced to the reaction system in a manner analogous to photoredox catalysis. These reactions feature the ability to generate high-value radicals that do not require harsh reaction conditions of anhydrous and anaerobic conditions, an expensive photocatalyst, and the use of solvents, which renders these transformations highly industrially applicable. In addition, mechanoredox chemistry is also an emerging interdisciplinary research field that combines material chemistry with synthetic chemistry to create more useful reactions. This review provides a comprehensive summary of progress to date in the specific transformation and related mechanisms of piezoelectric- mediated mechanoredox reactions by ball milling in organic synthesis.

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