Synthesis of Phosphorus, Arsenic and Antimony Ylides Containing the 1,3- Dimethyl-2,4,6(1H,3H,5H)-pyrimidinetrione Fragments

Title: Synthesis of Phosphorus, Arsenic and Antimony Ylides Containing the 1,3- Dimethyl-2,4,6(1H,3H,5H)-pyrimidinetrione Fragments

Volume: 6 Issue: 1

Author(s): Kamal Sweidan, Ahmed Al-Sheikh, Bassam Sweileh, Mahmoud Sunjuk and Norbert Kuhn

Affiliation:

Keywords: 1,3-dimethyl-2, 4,6(1H,3H,5H)-pyrimidinetrione (1,3-dimethylbarbituric acid), nuclear magnetic resonance, synthesis, zwitterionic state

Abstract: The ylides Ph3E-C6H6N2O3 (7, E = P (a), As (b), Sb (c)) have been prepared through the reaction of Ph3E and 5- bromo-1,3-dimethyl-2,4,6(1H,3H,5H)-pyrimidinetrione (5-bromo-1,3-dimethylbarbituric acid) 6 in the presence of triethylamine. Their characterisation was performed by nuclear magnetic resonance (NMR), mass spectrometry (MS) and elemental analysis.

Cite this article as:

Sweidan Kamal, Al-Sheikh Ahmed, Sweileh Bassam, Sunjuk Mahmoud and Kuhn Norbert, Synthesis of Phosphorus, Arsenic and Antimony Ylides Containing the 1,3- Dimethyl-2,4,6(1H,3H,5H)-pyrimidinetrione Fragments, Letters in Organic Chemistry 2009; 6 (1) . https://dx.doi.org/10.2174/157017809787003106