Abstract
Enynols were hydroaluminated and cross coupled with aryl iodides. Reduction of the yne portion of the enynol is a serious side reaction so reaction conditions to minimize reduction and maximize cross coupling were investigated in detail.
Keywords: Hydroalumination, cross coupling, enynols, ynols
Letters in Organic Chemistry
Title: Substituted Dienols from Palladium Catalyzed Coupling of Hydroaluminated Enynols with Aryl Iodides
Volume: 5 Issue: 3
Author(s): Kenneth E. Crook, Jin Nie and Mark E. Welker
Affiliation:
Keywords: Hydroalumination, cross coupling, enynols, ynols
Abstract: Enynols were hydroaluminated and cross coupled with aryl iodides. Reduction of the yne portion of the enynol is a serious side reaction so reaction conditions to minimize reduction and maximize cross coupling were investigated in detail.
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Cite this article as:
Crook E. Kenneth, Nie Jin and Welker E. Mark, Substituted Dienols from Palladium Catalyzed Coupling of Hydroaluminated Enynols with Aryl Iodides, Letters in Organic Chemistry 2008; 5 (3) . https://dx.doi.org/10.2174/157017808783955790
DOI https://dx.doi.org/10.2174/157017808783955790 |
Print ISSN 1570-1786 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6255 |
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