Facile Synthesis of Unsymmetrically Substituted Ferrocene-1,1 ’ -bis- Carboxamides via Homogeneous Catalytic Carbonylation

Arpad      Kuik; Zsolt      Szarka; Rita      Skoda-Foldes; Laszlo      Kollar

doi:10.2174/1570178043488554

Abstract

The synthesis of unsymmetrical ferrocene 1,1 ’ -diamides via homogeneous catalytic aminocarbonylation of 1,1 ’ -diiodo-ferrocene is described. The products were obtained in good yields in a one-pot reaction by using two different secondary amines as nucleophiles simultaneously.

Keywords: ferrocene diamides, homogeneous catalysis, carbonylation, pd-catalysts

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Letters in Organic Chemistry

Title: Facile Synthesis of Unsymmetrically Substituted Ferrocene-1,1 ’ -bis- Carboxamides via Homogeneous Catalytic Carbonylation

Volume: 1 Issue: 2

Author(s): Arpad Kuik, Zsolt Szarka, Rita Skoda-Foldes and Laszlo Kollar

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Keywords: ferrocene diamides, homogeneous catalysis, carbonylation, pd-catalysts

Abstract: The synthesis of unsymmetrical ferrocene 1,1 ’ -diamides via homogeneous catalytic aminocarbonylation of 1,1 ’ -diiodo-ferrocene is described. The products were obtained in good yields in a one-pot reaction by using two different secondary amines as nucleophiles simultaneously.

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Kuik Arpad, Szarka Zsolt, Skoda-Foldes Rita and Kollar Laszlo, Facile Synthesis of Unsymmetrically Substituted Ferrocene-1,1 ’ -bis- Carboxamides via Homogeneous Catalytic Carbonylation, Letters in Organic Chemistry 2004; 1 (2) . https://dx.doi.org/10.2174/1570178043488554