Synthesis of Luminescent N-Arylcarbazoles by Copper Bronze-Mediated Reaction

M.      Martinez-Palau; E.      Perea; F.      Lopez-Calahorra; D.      Velasco

doi:10.2174/1570178043401261

Abstract

A copper bronze-mediated carbazole arylation reaction under mild reaction conditions is reported. Yields of 9-arylcarbazoles achieved are nearly quantitative and almost independent of the nature of the substitution on the carbazole or the aryl halide. A series of 9-arylcarbazole derivatives have been synthesised and their luminescence studied.

Keywords: 9-arylcarbazole, arylation, copper-bronze catalysis, semiempirical calculations, luminescence

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Letters in Organic Chemistry

Title: Synthesis of Luminescent N-Arylcarbazoles by Copper Bronze-Mediated Reaction

Volume: 1 Issue: 3

Author(s): M. Martinez-Palau, E. Perea, F. Lopez-Calahorra and D. Velasco

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Keywords: 9-arylcarbazole, arylation, copper-bronze catalysis, semiempirical calculations, luminescence

Abstract: A copper bronze-mediated carbazole arylation reaction under mild reaction conditions is reported. Yields of 9-arylcarbazoles achieved are nearly quantitative and almost independent of the nature of the substitution on the carbazole or the aryl halide. A series of 9-arylcarbazole derivatives have been synthesised and their luminescence studied.

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Martinez-Palau M., Perea E., Lopez-Calahorra F. and Velasco D., Synthesis of Luminescent N-Arylcarbazoles by Copper Bronze-Mediated Reaction, Letters in Organic Chemistry 2004; 1 (3) . https://dx.doi.org/10.2174/1570178043401261