Multivalent Recognition of Flavin Derivatives Using Polymer Scaffolds

Joseph   B.   Carroll; Mark      Gray; Kevin   M.   Bardon; Hiroshi      Nakade; Vincent   M.   Rotello

doi:10.2174/1570178043400974

Abstract

Random copolymers of polystyrene were functionalized with diamidopyridine and anthracene recognition elements. Cooperative recognition between isobutyl flavin “guest” molecules and mixed recognition unit modified “host” copolymers was observed arising from a combination of aromatic stacking and hydrogen bonding interactions.

Keywords: cooperative non-covalent interactions, hydrogen bonding, stacking, supramolecular polymers

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Letters in Organic Chemistry

Title: Multivalent Recognition of Flavin Derivatives Using Polymer Scaffolds

Volume: 1 Issue: 3

Author(s): Joseph B. Carroll, Mark Gray, Kevin M. Bardon, Hiroshi Nakade and Vincent M. Rotello

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Keywords: cooperative non-covalent interactions, hydrogen bonding, stacking, supramolecular polymers

Abstract: Random copolymers of polystyrene were functionalized with diamidopyridine and anthracene recognition elements. Cooperative recognition between isobutyl flavin “guest” molecules and mixed recognition unit modified “host” copolymers was observed arising from a combination of aromatic stacking and hydrogen bonding interactions.

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Carroll B. Joseph, Gray Mark, Bardon M. Kevin, Nakade Hiroshi and Rotello M. Vincent, Multivalent Recognition of Flavin Derivatives Using Polymer Scaffolds, Letters in Organic Chemistry 2004; 1 (3) . https://dx.doi.org/10.2174/1570178043400974