A One-Pot Synthesis of D-Ribonucleosides Using Natural Phosphate Doped with KI in HMDS

Hassan   B.   Lazrek; Driss      Ouzebla; Abdellali      Rochdi; Nezha      Redwane; Jean-Jacques      Vasseur

doi:10.2174/157017806776114531

Abstract

Potassium iodide supported on natural phosphate in HMDS was used as a promotor in the condensation of 1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribofuranose with trimethylsilylated nucleobases, under mild conditions, to provide several D-ribonucleosides.

Keywords: Natural phosphate, potassium iodide, nucleosides

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Letters in Organic Chemistry

Title: A One-Pot Synthesis of D-Ribonucleosides Using Natural Phosphate Doped with KI in HMDS

Volume: 3 Issue: 4

Author(s): Hassan B. Lazrek, Driss Ouzebla, Abdellali Rochdi, Nezha Redwane and Jean-Jacques Vasseur

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Keywords: Natural phosphate, potassium iodide, nucleosides

Abstract: Potassium iodide supported on natural phosphate in HMDS was used as a promotor in the condensation of 1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribofuranose with trimethylsilylated nucleobases, under mild conditions, to provide several D-ribonucleosides.

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Lazrek B. Hassan, Ouzebla Driss, Rochdi Abdellali, Redwane Nezha and Vasseur Jean-Jacques, A One-Pot Synthesis of D-Ribonucleosides Using Natural Phosphate Doped with KI in HMDS, Letters in Organic Chemistry 2006; 3 (4) . https://dx.doi.org/10.2174/157017806776114531