Solvent Dependent Benzylic Radical Bromination of Aromatic Sulfonyl Chlorides

Laura      Quartara; Maria      Altamura; Annalisa      Guerri; Rossano      Nannicini; Martina      Gensini; Gianluca      Battaglia

doi:10.2174/157017806775789958

Abstract

We have studied the solvent dependent radical bromination of toluene sulfonyl chlorides. The use of acetonitrile allows to avoid chlorinated solvents and to improve the yield and the reproducibility of the process.

Keywords: aromatic sulfonyl chloride, benzyl bromide, N-bromosuccinimide, Radical bromination

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Letters in Organic Chemistry

Title: Solvent Dependent Benzylic Radical Bromination of Aromatic Sulfonyl Chlorides

Volume: 3 Issue: 3

Author(s): Laura Quartara, Maria Altamura, Annalisa Guerri, Rossano Nannicini, Martina Gensini and Gianluca Battaglia

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Keywords: aromatic sulfonyl chloride, benzyl bromide, N-bromosuccinimide, Radical bromination

Abstract: We have studied the solvent dependent radical bromination of toluene sulfonyl chlorides. The use of acetonitrile allows to avoid chlorinated solvents and to improve the yield and the reproducibility of the process.

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Quartara Laura, Altamura Maria, Guerri Annalisa, Nannicini Rossano, Gensini Martina and Battaglia Gianluca, Solvent Dependent Benzylic Radical Bromination of Aromatic Sulfonyl Chlorides, Letters in Organic Chemistry 2006; 3 (3) . https://dx.doi.org/10.2174/157017806775789958