Abstract
The molecular recognition properties of a novel calix[4]arene receptor fixed in a 1,3-alternate conformation bearing two dipyridyl moieties towards organic molecules containing hydroxylic (phenolic or alcoholic) or amino functionalities have been investigated by 1H NMR spectroscopy in CDCl3. The novel receptor selectively recognizes by hydrogen bonding only molecules having two OH phenolic groups.
Keywords: Calixarenes, Molecular recognition, Hydrogen bonding, Diphenols
Letters in Organic Chemistry
Title: Hydrogen Bonding Molecular Recognition of Diphenols by a Novel 1,3- Alternate Calix[4]arene Receptor Bearing Two Dipyridyl Moieties
Volume: 3 Issue: 1
Author(s): Salvatore Gentile, Fabio G. Gulino, Domenico Sciotto and Carmelo Sgarlata
Affiliation:
Keywords: Calixarenes, Molecular recognition, Hydrogen bonding, Diphenols
Abstract: The molecular recognition properties of a novel calix[4]arene receptor fixed in a 1,3-alternate conformation bearing two dipyridyl moieties towards organic molecules containing hydroxylic (phenolic or alcoholic) or amino functionalities have been investigated by 1H NMR spectroscopy in CDCl3. The novel receptor selectively recognizes by hydrogen bonding only molecules having two OH phenolic groups.
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Cite this article as:
Gentile Salvatore, Gulino G. Fabio, Sciotto Domenico and Sgarlata Carmelo, Hydrogen Bonding Molecular Recognition of Diphenols by a Novel 1,3- Alternate Calix[4]arene Receptor Bearing Two Dipyridyl Moieties, Letters in Organic Chemistry 2006; 3 (1) . https://dx.doi.org/10.2174/157017806774964396
DOI https://dx.doi.org/10.2174/157017806774964396 |
Print ISSN 1570-1786 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6255 |
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