Highlights in Organic Chemistry [ Exploitation of Acetylenic Coupling Reactions in the Synthesis of Extended Tetrathiafulvalenes]

Mogens   B.   Nielsen

doi:10.2174/157017806774964477

Abstract

Acetylenic coupling reactions allow for construction of a wide variety of redox-active extended tetrathiafulvalenes (TTFs) from simple acetylenic dithiafulvene building blocks. This highlight covers the synthesis of such acetylenic TTF scaffolds with oligoyne, di-, tri-, or tetraethynylethene cores.

Keywords: tetrathiafulvalene, di/tri/tetraethynylethene, C-C coupling, Alkynes

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Letters in Organic Chemistry

Title: Highlights in Organic Chemistry [ Exploitation of Acetylenic Coupling Reactions in the Synthesis of Extended Tetrathiafulvalenes]

Volume: 3 Issue: 1

Author(s): Mogens B. Nielsen

Affiliation:

Keywords: tetrathiafulvalene, di/tri/tetraethynylethene, C-C coupling, Alkynes

Abstract: Acetylenic coupling reactions allow for construction of a wide variety of redox-active extended tetrathiafulvalenes (TTFs) from simple acetylenic dithiafulvene building blocks. This highlight covers the synthesis of such acetylenic TTF scaffolds with oligoyne, di-, tri-, or tetraethynylethene cores.

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Nielsen B. Mogens, Highlights in Organic Chemistry [ Exploitation of Acetylenic Coupling Reactions in the Synthesis of Extended Tetrathiafulvalenes], Letters in Organic Chemistry 2006; 3 (1) . https://dx.doi.org/10.2174/157017806774964477