Abstract
In this work, we investigated the effect of film thickness on the structure and
properties of Ti-N films deposited by magnetron sputtering. The structural properties of
Ti-N films were described, followed by a detailed investigation into their mechanical
properties by using theoretical and experimental analysis. The theoretical calculation
presented the Rocksalt TiN structure with a lattice parameter of about 4.255 Å,
confirmed by X-ray diffraction. The experimental analysis revealed that the structure
and the hardness of TiN films varied in a wide range when increasing the film
thickness. The structure morphology also changed from a rough to a dense surface and
a smooth structure. The hardness and Young modulus of the TiN film reach maximum
values of about 26 GPa and 445 GPa, respectively, and then decrease with increasing
the film’s thickness. The theoretical values of the hardness and young modulus are in
excellent agreement with those obtained for the Ti-N thick films.