Smart Materials Design for Electromagnetic Interference Shielding Applications

Fabrication and Microwave Shielding Properties of Free-Standing Conducting Polymer-Carbon Fiber Thin Sheets

Author(s): Rakesh Kumar* and S K Dhawan

Pp: 355-410 (56)

DOI: 10.2174/9789815036428122010011

* (Excluding Mailing and Handling)

Abstract

EMI is a 20th-century radiation pollution that not only results in various health hazards but also weakens the electronic system's performance. With the rapid global development in various fields, this problem is increasing consistently. To ensure the uninterrupted performance of electronic gadgets and avoid the effects on human health, EMI shielding has become a necessity. In the recent past, a large number of materials having a wide range of conductivity and good electromagnetic attributes have been exploited for EMI shielding applications. Initially used metallic shields, due to their high cost & weight, corrosion propensity, and reflection-based shielding, have been replaced by various types of materials. Among them, intrinsically conducting polymers (ICPs) like polyaniline, polythiophene, polypyrrole, etc., and their composites with various types of conductive and/or magnetic fillers have played a significant role. Among all the conducting polymers, polyaniline has been studied the most due to its special properties like moderately high conductivity, ease of synthesis, proton doping, low cost, and high environmental stability. Most of the developments related to EMI shielding have been focused on the synthesis of new materials with high shielding effectiveness (SE). For this purpose, polyaniline and its composites have been widely explored due to its appropriate properties. But the commercial use of polyaniline for EMI shielding applications has always been hampered due to its infusibility and limited processability. Also, limited work has been done for the fabrication of polyaniline composites in the form of sheets that have sufficient SE along with improved thermal and mechanical stability. The work presented in this chapter is based on the fabrication of lightweight, thin sheets of polyaniline composites for EMI shielding application in the X-band of microwave range (8.2-12.4 GHz). The polyaniline-CFnovolac (PACN) composite sheets thus obtained were finally tested for EMI shielding applications using vector network analyzer (VNA) in the X-band of microwave range. Characterization of all the composites and/or their sheets was done by UV-vis, FT-IR, SEM, TGA, electrical conductivity (standard four-probe method), flexural strength, and flexural modulus measurements.

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      • 13. app/Models/UserAccess/UserAccess.php:1266
      • 14. app/Http/Controllers/ChapterController.php:1518
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Trial Access" as access_base_text, CASE j.type WHEN 111 THEN true ELSE false END as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"chapter" as access_level, j.chapter_id from `user_access_chapter_trail` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316524592 and j.to_ip >=316524592 )) and ((j.from_date <= 1740497465 and j.to_date >= 1740497465 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.chapter_id = 18149) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Subscribed" as access_base_text, false as terms_popup, "S" as content_download_type, null as restricted_user_access_key, null as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"chapter" as access_level, j.chapter_id from `user_access_chapter_corporate` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316524592 and j.to_ip >=316524592 )) and ((j.from_date <= 1740497465 and j.to_date >= 1740497465 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.chapter_id = 18149) union (select j.user_access_id,j.volume_id,j.user_id,j.from_ip,j.to_ip,j.type,j.track,"Token Based Access" as access_base_text, false as terms_popup, "R" as content_download_type, j.uc_id as restricted_user_access_key, "v" as restricted_user_access_type, CASE j.track WHEN 0 THEN false ELSE true END as tracksAccessByVolume,"chapter" as access_level, j.chapter_id from `user_access_chapter_token` as `j` inner join `user_access_info` as `info` on `j`.`user_access_id` = `info`.`user_access_id` where ((j.from_ip <= 316524592 and j.to_ip >=316524592 )) and ((j.from_date <= 1740497465 and j.to_date >= 1740497465 and j.perpetual= 0) or (j.from_date is null and j.to_date is null and j.perpetual= 1)) and j.chapter_id = 18149)
      660μsalphaeurekaselec_live_10_06_2022UserAccess.php#1266
      Backtrace
      • 13. app/Models/UserAccess/UserAccess.php:1266
      • 14. app/Http/Controllers/ChapterController.php:1549
      • 15. vendor/laravel/framework/src/Illuminate/Routing/Controller.php:54
      • 16. vendor/laravel/framework/src/Illuminate/Routing/ControllerDispatcher.php:43
      • 17. vendor/laravel/framework/src/Illuminate/Routing/Route.php:260
    • select b.banner_link, b.banner_name, b.banner_script, b.banner_remarks, b.banner_file_name, b.banner_placement, bd.content_type, bd.content_id from `tbl_banner` as `b` inner join `tbl_banner_detail` as `bd` on `bd`.`banner_id` = `b`.`banner_id` inner join `users` as `u` on `u`.`id` = `b`.`updated_by` where `b`.`banner_ebook` = 1 and `bd`.`content_type` = 'B' and `bd`.`content_id` = 3428 and `b`.`banner_from_date` <= 1740497465 and `b`.`banner_to_date` >= 1740497465 and `b`.`banner_status` = 'A' order by `b`.`banner_id` desc
      1.09msalphaeurekaselec_live_10_06_2022Banner.php#95
      Bindings
      • 0: 1
      • 1: B
      • 2: 3428
      • 3: 1740497465
      • 4: 1740497465
      • 5: A
      Backtrace
      • 13. app/Models/Banner.php:95
      • 14. app/Http/helpers.php:404
      • 17. vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:124
      • 18. vendor/laravel/framework/src/Illuminate/View/Engines/PhpEngine.php:58
      • 19. vendor/laravel/framework/src/Illuminate/View/Engines/CompilerEngine.php:73
    • select count(*) as aggregate from `uc_cart_products` where cart_id='ec0bacec4ed33302f66e09ad194dade8'
      210μsalphaeurekaselec_live_10_06_2022Cart.php#271
      Backtrace
      • 15. app/Models/Cart.php:271
      • 16. view::layouts._header:260
      • 18. vendor/laravel/framework/src/Illuminate/Filesystem/Filesystem.php:124
      • 19. vendor/laravel/framework/src/Illuminate/View/Engines/PhpEngine.php:58
      • 20. vendor/laravel/framework/src/Illuminate/View/Engines/CompilerEngine.php:73
    App\Models\Chapter
    1Chapter.php#?
    App\Models\Ebook
    1Ebook.php#?
        _token
        z7xAUUe5wmWSjVflErQYb7Y3blN9apUhAuiORI45
        _previous
        array:1 [ "url" => "https://alpha.eurekaselect.com/chapter/18149" ]
        _flash
        array:2 [ "old" => [] "new" => [] ]
        uc_cart_id
        ec0bacec4ed33302f66e09ad194dade8
        PHPDEBUGBAR_STACK_DATA
        []
        path_info
        /chapter/18149
        status_code
        200
        
        status_text
        OK
        format
        html
        content_type
        text/html; charset=UTF-8
        request_query
        []
        
        request_request
        []
        
        request_headers
        0 of 0
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        request_cookies
        0 of 0
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        response_headers
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        ClearShow all
        Date ↕MethodURLData
        #12025-02-25 15:31:05GET/chapter/18149112192