摘要
据报道，作者实验室已对基于放射状生长的大分子和核心起始的硼烷外围装饰了邻氨基甲酸酯和金属氨基甲酸酯的微型综述进行了报道。审查分为四个部分。它们中的三个与这些大的含硼分子的设计和合成有关，第四个涉及阴离子金属碳硼烷分子的独特性能，从而为它们在医学应用中的应用前景提供了可能。它们的独特稳定性以及其几何和电子性质，以及1,2-氯-C2B10H12（邻-碳环烷）的精确空间结构，可能并入许多取代基：在碳（Cc），在硼以及在碳和硼的两个顶点处均表明，该簇是有机化合物无法实现的新颖应用的创新构件或平台。从荧光核（例如1,3,5-三芳基苯或中卟啉）生长的聚（芳基醚）树状聚合物已用硼簇装饰，以获得富含硼的树状聚合物。八碳倍半硅氧烷立方体已被用作其径向生长的核心，以获取富含硼的大分子。钴双双糖脂簇的独特性质包括：i）在水中自组装以产生单层纳米囊泡； ii）穿过脂质双层膜； iii）与膜细胞相互作用； iv）通过拉曼和荧光技术促进其在细胞内的可视化v）详细讨论了它们作为“体内”成像的分子平台的用途。
关键词: 碳硼烷，金属碳硼烷，硼烷，树枝状大分子，大分子，细胞成像，标记，抗菌剂，荧光探针，八硅倍半氧烷，光致发光。
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