Formation of Highly Functionalized Hydrindanes and Hydroazulenes via Polyene Cyclization Promoted by the Cross Conjugated α-Carbomethoxy Enone System

Hsing-Jang      Liu; Daqing      Sun; Floria      Roa-Gutierrez; Kak-Shan      Shia

doi:10.2174/1570178054038966

Abstract

The polyene cyclization promoted by the cross conjugated α-carbomethoxy enone system has been successfully applied to facilitate the construction of the hydridane and hydroazulene framework containing a high level of functionalization.

Keywords: polyenes, cyclization, bicyclic aliphatic compounds, hydridanes, hydroazulenes, steroidal compounds

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Letters in Organic Chemistry

Title: Formation of Highly Functionalized Hydrindanes and Hydroazulenes via Polyene Cyclization Promoted by the Cross Conjugated α-Carbomethoxy Enone System

Volume: 2 Issue: 4

Author(s): Hsing-Jang Liu, Daqing Sun, Floria Roa-Gutierrez and Kak-Shan Shia

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Keywords: polyenes, cyclization, bicyclic aliphatic compounds, hydridanes, hydroazulenes, steroidal compounds

Abstract: The polyene cyclization promoted by the cross conjugated α-carbomethoxy enone system has been successfully applied to facilitate the construction of the hydridane and hydroazulene framework containing a high level of functionalization.

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Liu Hsing-Jang, Sun Daqing, Roa-Gutierrez Floria and Shia Kak-Shan, Formation of Highly Functionalized Hydrindanes and Hydroazulenes via Polyene Cyclization Promoted by the Cross Conjugated α-Carbomethoxy Enone System, Letters in Organic Chemistry 2005; 2 (4) . https://dx.doi.org/10.2174/1570178054038966