Abstract
Over the past decade, chiral Lewis base-catalysed cycloadditions has brought about numerous methods for the enantioselective synthesis of carbocycles and heterocycles. This short review covers some of the advances made in the area of absolute stereocontrol in this higher order cycloaddition.
Keywords: Cycloaddition, organocatalysis, asymmetric, Lewis base, phosphine catalysts, amine catalysts, organic synthesis, asymmetric cycloaddition, Diels-Alder transformations, carbocycles, heterocycles, cyclopropanes, alkaloids, bioactive molecules, stereochemistry
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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