Login Register Cart 0
Generic placeholder image

Current Physical Chemistry

Editor-in-Chief

ISSN (Print): 1877-9468
ISSN (Online): 1877-9476

Back
Journal Home About Journal Editorial Board Journal Insight Current Issue Volumes/Issues
Subscribe
Research Article

Thermodynamic Properties of Pyridine Based 1,3,4-Oxadiazole Scaffolds

Author(s): Dinesh Godhani*, Anwar Saiyad, Umang Mehta, Kuldip Parmar and Jignasu Mehta

Volume 14, Issue 1, 2024

Published on: 07 December, 2023

Page: [54 - 66] Pages: 13

DOI: 10.2174/0118779468275261231117053704

Price: $65

Abstract

Background: The present work describes the synthesis, characterization, and thermo-acoustical parameters of binary solutions of 1-(2-(4-fluorophenyl)-5-(pyridin-4-yl)- 1,3,4-oxadiazol-3(2H)-yl)-3-(pyridin-2-yl)prop-2-en-1-one, (AS1-08) and 1-(2-(4- methoxyphenyl)-5-(pyridin-4-yl)-1,3,4-oxadiazol-3(2H)-yl)-3-(pyridin-2-yl)prop-2-en-1- one, (AS1-12) in dimethyl sulfoxide (DMSO) and N, N-dimethylformamide (DMF) were estimated.

Methods: Viscosity, ultrasonic velocity, and density methods at different solvents (DMSO and DMF) and different temperatures (298.15, 308.15, and 318.15 K) were used during the experimental research work.

Results: Some acoustic parameters such as adiabatic compressibility (κs), intermolecular free path length (Lf), Rao’s molar sound function (Rm), Van der Waals constant (b), internal pressure (π), free volume (Vf) and solvation number (Sn) were calculated. The results obtained were interpreted in terms of solute-solvent and solute-solute interactions.

Conclusion: The thermodynamic and various acoustical properties were determined at three different temperatures viz. (298.15, 308.15, and 318.15 K) at atmospheric pressure. Likewise, the similarity between experimental results of the binary solutions was studied to analyze how the change in the structural modification and solvent changes the values of Gibbs energy of activation (ΔG*), enthalpy of activation (ΔH*), and entropy of activation (ΔS*).

« Previous Next »
Graphical Abstract

[1]
Raijada, A.; Rathod, A.; Ghumara, R.; Patel, C.; Bhola, R.; Bijani, S.; Jain, V. Density, viscosity and sound speed of 4, 4′-(Cyclohexane-1, 1-diyl) bis (2,6-dibromophenol) in 1,4-dioxane, ethyl acetate and tetrahydrofuran at different temperatures. Chem. Afr., 2023, 1-13.
[http://dx.doi.org/10.1007/s42250-023-00699-z]
[2]
Dhingra, L.; Prakash Dubey, G. Thermodynamic properties, viscosity modelling and FTIR studies of binary liquid mixtures of 2-isopropoxy ethanol with amines at different temperatures. J. Chem. Thermodyn., 2023, 182, 107041.
[http://dx.doi.org/10.1016/j.jct.2023.107041]
[3]
Shankar, K.N.; Adhikari, J.; Noronha, S.B. Computer aided solvent selection and design for the efficient extraction of a pharmaceutical molecule. Can. J. Chem. Eng., 2019, 97(S1), 1605-1618.
[http://dx.doi.org/10.1002/cjce.23395]
[4]
Li, W.H.; Yang, J.; Wang, D. Long-range interactions in diatomic catalysts boosting electrocatalysis. Angew. Chem. Int. Ed., 2022, 61(52), e202213318.
[http://dx.doi.org/10.1002/anie.202213318] [PMID: 36199272]
[5]
Godhani, D.R.; Dobariya, P.B.; Sanghani, A.M.; Jogel, A.A.; Mehta, J.P. Effect of temperature and solvents on thermo-physical properties of 1,3,4-oxadiazole derivative at atmospheric pressure. J. Mol. Liq., 2013, 180, 179-186.
[http://dx.doi.org/10.1016/j.molliq.2013.01.017]
[6]
Zhong, S.; Nsengiyumva, W. Ultrasonic testing techniques for nondestructive evaluation of fiber reinforced composite structures. In: In Nondestructive Testing and Evaluation of Fiber-Reinforced Composite Structures; Springer: Singapore, 2022.
[http://dx.doi.org/10.1007/978-981-19-0848-4_4]
[7]
Godhani, D.R.; Jogel, A.A.; Mulani, V.B.; Sanghani, A.M.; Kukadiya, N.B.; Mehta, J.P. Effect of temperature and solvent on molecular interactions of 1, 2, 4-triazole derivative. Asian J. Res. Chem, 2018, 11(1), 32-36.
[http://dx.doi.org/10.5958/0974-4150.2018.00007.X]
[8]
Godhani, D.R.; Mulani, V.B.; Mehta, J.P.; Kukadiya, N.B. Synthesis and antimicrobial evolution of some new benzotriazole substituted 1, 3, 4-thiadiazoles. World Sci. News, 2018, (100), 51-60.
[9]
Godhani, D.R.; Mehta, U.P.; Mehta, J.P. Thermo-acoustic studies of thiazolidin one substituted 1, 2, 4-triazole derivatives. J. Pure Appl. Ultrason, 2021, 43, 17-26.
[10]
Gazmeh, M.; Khajenoori, M.; Yousefi-Nasab, S. Effect of temperature on curcumin solubility in a pressurized hot water solvent: Experimental and molecular dynamics simulation. Int. Commun. Heat Mass Transf., 2023, 146, 106918.
[http://dx.doi.org/10.1016/j.icheatmasstransfer.2023.106918]
[11]
Parmar, D.; Wazzan, N.; Kumar, N.; Rani, M.; Issaoui, N. Experimental, theoretical, computational and spectroscopic analysis in binary liquid mixtures containing 1-propanol and C-1 to C-4 alkyl acetates (T = 298.15–318.15 K): Physicochemical properties and molecular interaction studies. J. Mol. Liq., 2023, 381, 121829.
[http://dx.doi.org/10.1016/j.molliq.2023.121829]
[12]
Bhadane, S.J.; Patil, S.R. Study of molecular interactions of monoethanolamine with some higher alcohols at 298.15 K. Tenside Surfactants Deterg., 2023, 60(1), 13-20.
[http://dx.doi.org/10.1515/tsd-2022-2430]
[13]
Keshapolla, D.; Gardas, R.L. Apparent molar volumes and isentropic compressions of benzylalkylammonium ionic liquids in dimethylsulfoxide from 293.15 K to 328.15 K. Fluid Phase Equilib., 2014, 383(383), 32-42.
[http://dx.doi.org/10.1016/j.fluid.2014.09.022]
[14]
Papamatthaiakis, D.; Aroni, F.; Havredaki, V. Isentropic compressibilities of (amide+ water) mixtures: a comparative study. J. Chem. Thermodyn., 2008, 40(1), 107-118.
[http://dx.doi.org/10.1016/j.jct.2007.05.015]
[15]
Shekaari, H.; Bezaatpour, A.; Soltanpour, A. Partial molar volumes of N, N′-1, 2-ethyl-bis (salicyladimine) Schiff base (Salen) in organic solvents at T(283.15 to 318.15). K. J. Chem. Eng. Data, 2010, 55(12), 5927-5931.
[16]
Syal, V.K.; Patial, B.S.; Chauhan, S. Indian J. Pure Appl. Phy., 1999, 37, 366-370.
[17]
Gokavi, G.S.; Raju, J.R.; Aminabhavi, T.M.; Balundgi, R.H.; Muddapur, M.V. Viscosities and densities of binary liquid mixtures of dimethyl sulfoxide with chlorobenzene, pyridine, and methyl ethyl ketone at 25, 35, 45 and 55.degree. C. J. Chem. Eng. Data, 1986, 31(1), 15-18.
[http://dx.doi.org/10.1021/je00043a004]
[18]
Pal, A.; Kumar, A. Excess molar volumes and kinematic viscosities for binary mixtures of dipropylene glycol monobutyl ether and dipropylene glycol tert-butyl ether with 2-pyrrolidinone, N-methyl-2-pyrrolidinone, N, N-dimethylformamide, and N, N-dimethylacetamide at 298.15 K. J. Chem. Eng. Data, 2005, 50(3), 856-862.
[19]
Baluja, S.; Shah, A. Acoustical studies of some derivatives of 4-amino antipyrene in 1, 4-dioxane and dimethylformamide at 318.15 K. Fluid Phase Equilib., 2004, 215(1), 55-59.
[http://dx.doi.org/10.1016/S0378-3812(03)00355-8]

Rights & Permissions Print Cite
© 2024 Bentham Science Publishers | Privacy Policy