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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Research Article

Novel Series of Peripherally Phthalocyanines (Zn, Pd and Cu): Spectroscopic Studies

Author(s): Asma Rahali*, Verónica Almeida-Marrero, Andrés de la Escosura, Tomás Torres and Raoudha Abderrahim*

Volume 20, Issue 7, 2023

Published on: 07 February, 2023

Page: [647 - 656] Pages: 10

DOI: 10.2174/1570178620666221227162819

Price: $65

Abstract

A new series of metallophthalocyanines (MPc) containing metals such as : Zn (II), Cu (II) and, Pd (II) were designed, synthesized, and characterized, using MS, IR and UV-Vis spectroscopy. A Suzuki cross-coupling reaction was investigated by using the Pd(dppf)Cl2 as a catalyst and cesium carbonate as a base to improve the yield of the precursor 2.6-di(pyridin-3-yl)- phenyl benzyl ether. The changes of metals, substituents, and positions increases the Q-band value from the monosubstituted to the octa-substituted macrocycles, and from Pd, to Cu to Zn complexes. All MPc showed quite similar IR spectra.

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