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Current Organic Synthesis

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ISSN (Print): 1570-1794
ISSN (Online): 1875-6271

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Review Article

Palladium-Catalyzed Aminocarbonylation of Aryl Halides

Author(s): Cheriya Mukkolakkal Abdulla Afsina, Rose Mary Philip, Padinjare Veetil Saranya and Gopinathan Anilkumar*

Volume 20, Issue 3, 2023

Published on: 26 August, 2022

Page: [308 - 331] Pages: 24

DOI: 10.2174/1570179419666220430150122

Price: $65

Abstract

Palladium-catalyzed organic reactions are ubiquitous due to their high efficiency in coupling reactions and have wide applications in synthetic chemistry. Their widespread use in organic synthesis has been attributed to moderate conditions associated with reactions and tolerance to different types of functional groups. Palladium-catalysts are extensively used in aminocarbonylation of aryl halides for the synthesis of amides and have found a wide variety of applications in pharmaceuticals, agrochemicals, petrochemicals, materials, polymers, etc. In this review, we summarize the recent advances in the synthesis of amides via palladium-catalyzed aminocarbonylation of aryl halides, and cover literature from 2010 to 2021.

Keywords: Aminocarbonylation, aryl halides, amines, CO, palladium catalyst, amide synthesis.

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Graphical Abstract

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