Abstract
Objectives: The work investigates the performance of intrinsic layers with and without band-gap tailoring in single-junction amorphous silicon-based photovoltaic cells. The work proposes single-junction amorphous silicon solar cells in which band-gap grading has been done between layers as well as within each layer for the first time.
Materials & Methods: The samples of hydrogenated amorphous silicon-germanium with different mole fractions are fabricated, and their band-gaps are validated through optical characterization and material characterization. A single-junction solar cell with an intrinsic layer made up of hydrogenated amorphous silicon (aSi:H) having a band-gap of 1.6 eV is replaced by continuously graded hydrogenated amorphous silicon-germanium (aSi1-xGexH) intrinsic bottom layers having band-gaps ranging from 0.9 eV to 1.5 eV. The proposed structure has been considered as a variant of previously designed single-junction band-gap tailored structures.
Results: The suitable utilization of band-gap tailoring on the intrinsic absorber layer aids more incident photons in energy conversion and thereby attain a better short circuit current density of 19.89 mA/cm2.
Keywords: Band-gap tailoring, intrinsic, layer, mole fraction, hydrogenated amorphous silicon-germanium, short circuit, current density, conversion efficiency.
Graphical Abstract
[http://dx.doi.org/10.1016/j.tsf.2003.11.014]
[http://dx.doi.org/10.1109/55.119165]
[http://dx.doi.org/10.1149/1.2718401]
[http://dx.doi.org/10.1063/1.88617]
[http://dx.doi.org/10.1155/2009/154059]
[http://dx.doi.org/10.1002/pip.2216]
[http://dx.doi.org/10.1002/pip.541]
[http://dx.doi.org/10.1016/j.rinp.2020.102940]
[http://dx.doi.org/10.2174/2210681209666190627152852]
[http://dx.doi.org/10.1016/j.jallcom.2015.10.235]
[http://dx.doi.org/10.1016/j.optmat.2015.11.012]
[http://dx.doi.org/10.1080/15421406.2013.851502]
[http://dx.doi.org/10.1016/0022-3093(87)90328-0]
[http://dx.doi.org/10.1143/JJAP.25.L54]
[http://dx.doi.org/10.1143/JJAP.28.5]
[http://dx.doi.org/10.1088/0741-3335/42/12B/326]
[http://dx.doi.org/10.1016/0025-5408(68)90023-8]
[http://dx.doi.org/10.1007/s10854-018-0470-6]
[http://dx.doi.org/10.1007/s12633-016-9527-4]