Applications of the Dess-Martin Oxidation in Total Synthesis of Natural Products

Majid    M.    Heravi; Tayebe       Momeni; Vahideh       Zadsirjan; Leila       Mohammadi
doi:10.2174/1570179417666200917102634
Abstract

Dess–Martin periodinane (DMP), a commercially available chemical, is frequently utilized as a mild oxidative agent for the selective oxidation of primary and secondary alcohols to their corresponding aldehydes and ketones, respectively. DMP shows several merits over other common oxidative agents such as chromiumand DMSO-based oxidants; thus, it is habitually employed in the total synthesis of natural products. In this review, we try to underscore the applications of DMP as an effective oxidant in an appropriate step (steps) in the multi-step total synthesis of natural products.
Keywords: Dess-Martin periodinane, DMP, oxidation, total synthesis, natural products, oxidation, alcohols, aldehydes, ketones.
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DOI https://dx.doi.org/10.2174/1570179417666200917102634	Print ISSN 1570-1794
Publisher Name Bentham Science Publisher	Online ISSN 1875-6271
Current Organic Synthesis

Applications of the Dess-Martin Oxidation in Total Synthesis of Natural Products

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