Abstract
Stereocontrolled formation of C–C bonds in polyfunctionalized carbohydrate derivatives, which are crucial synthetic intermediates, is sometimes very challenging. The application of low valent organometallic reagents for C–C bond formation in carbohydrate chemistry has recently attracted a great deal of attention, largely due to the mild reaction conditions required. We present here an overview of the application of different reductive C–C bond forming reactions in carbohydrate chemistry.
Keywords: C–C bond formation, barbier, reformatsky, pinacol coupling, single electron transfer (SET), carbohydrates
Current Organic Synthesis
Title:Applications of Barbier Type Reactions in Carbohydrate Chemistry
Volume: 10 Issue: 2
Author(s): Raquel G. Soengas and Amalia M. Estevez
Affiliation:
Keywords: C–C bond formation, barbier, reformatsky, pinacol coupling, single electron transfer (SET), carbohydrates
Abstract: Stereocontrolled formation of C–C bonds in polyfunctionalized carbohydrate derivatives, which are crucial synthetic intermediates, is sometimes very challenging. The application of low valent organometallic reagents for C–C bond formation in carbohydrate chemistry has recently attracted a great deal of attention, largely due to the mild reaction conditions required. We present here an overview of the application of different reductive C–C bond forming reactions in carbohydrate chemistry.
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Cite this article as:
G. Soengas Raquel and M. Estevez Amalia, Applications of Barbier Type Reactions in Carbohydrate Chemistry, Current Organic Synthesis 2013; 10 (2) . https://dx.doi.org/10.2174/1570179411310020001
DOI https://dx.doi.org/10.2174/1570179411310020001 |
Print ISSN 1570-1794 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6271 |
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