Abstract
Background: High concentration of phosphate has been threatening human health and the ecosystem. Adsorption is one of high-efficiency and low-cost techniques to reduce the concentration of phosphate. This mini review aims to summarize the recent development of adsorption materials for phosphate removal.
Method: We conducted a detailed search of “adsorption of phosphate” in the published papers and the public patents on the adsorbents for phosphate based on Web of Science database in the period from January 1 2012 to December 31 2017. The corresponding literature was carefully evaluated and analyzed.
Results: One hundred and forty one papers and twenty two recent patents were included in this review. An increased trend in scientific contributions was observed in the development of adsorption materials for phosphate removal. Three kinds of promising adsorbents: layered double hydroxides, natural materials, and metal oxides were paid special attention including removal mechanism, performance as well as the relationship between adsorption performance and structure. Both the chemical composition and the morphology play a key role in the removal capacity and rate.
Conclusion: The findings of this review confirm the importance of phosphate removal, show the development trend of high-performance and low-cost adsorption materials for phosphate removal, and provide a helpful guide to design and fabricate high-efficiency adsorbents.
Keywords: Adsorption process, layered double hydroxides, metal oxide, nanomaterials, natural materials, phosphate removal.
Graphical Abstract
[1]
Ahmed S, Guo Y, Huang R, Li D, Tang P, Feng Y. Hexamethylene tetramine-assisted hydrothermal synthesis of porous magnesium oxide for high-efficiency removal of phosphate in aqueous solution. J Environ Chem Eng 2017; 5: 4649-55.
[2]
Ahmed S, Iqbal A. Synthesis of 2D magnesium oxide nanosheets: A potential material for phosphate removal. Glob Challenges 2018; 2: 1800056.
[3]
Zhang Y, Guo X, Wu F, et al. Mesocarbon Microbead carbon-supported magnesium hydroxide nanoparticles: Turning spent Li-ion Battery anode into a highly efficient phosphate adsorbent for wastewater treatment. ACS Appl Mater Interfaces 2016; 8: 21315-25.
[4]
Tran NH, Urase T, Ngo HH, Hu J, Ong SL. Insight into metabolic and cometabolic activities of autotrophic and heterotrophic microorganisms in the biodegradation of emerging trace organic contaminants. Bioresour Technol 2013; 146: 721-31.
[5]
Smith VH, Tilman GD, Nekola JC. Eutrophication: Impacts of excess nutrient inputs on freshwater, marine, and terrestrial ecosystems. Environ Pollut 1999; 100: 179-96.
[6]
Rai J, Kumar D, Pandey LK, Yadav A, Gaur JP. Potential of cyanobacterial biofilms in phosphate removal and biomass production. J Environ Manage 2016; 177: 138-44.
[7]
Ahmed MB, Zhou JL, Ngo HH, Guo W, Thomaidis NS, Xu J. Progress in the biological and chemical treatment technologies for emerging contaminant removal from wastewater: A critical review. J Hazard Mater 2017; 323: 274-98.
[8]
Huang H, Liu J, Zhang P, Zhang D, Gao F. Investigation on the simultaneous removal of fluoride, ammonia nitrogen and phosphate from semiconductor wastewater using chemical precipitation. Chem Eng J 2017; 307: 696-706.
[9]
Huang W, Zhang Y, Li D. Adsorptive removal of phosphate from water using mesoporous materials: A review. J Environ Manage 2017; 193: 470-82.
[10]
Zhao J, Li Y, Zhang C, Zeng Q, Zhou Q. Sorption and degradation of bisphenol A by aerobic activated sludge. J Hazard Mater 2008; 155: 305-11.
[11]
Joss A, Andersen H, Ternes T, Richle PR, Siegrist H. Removal of estrogens in municipal wastewater treatment under aerobic and anaerobic conditions: consequences for plant optimization. Environ Sci Technol 2004; 38: 3047-55.
[12]
Clarke BO, Smith SR. Review of ‘emerging’ organic contaminants in biosolids and assessment of international research priorities for the agricultural use of biosolids. Environ Int 2011; 37: 226-47.
[13]
Chen P, He Y, Liu Y, et al. Pre-processing vehicle coating phosphorus
waste water, comprises e.g. collecting phosphate waste water
from sump, transferring into a reaction device, adding catalyst,
carrying out aeration, precipitating and performing ion exchange.
Chinese Patent 105585221, 2016
[14]
Ju X, Hou J, Tang Y, Sun Y, Zheng S, Xu Z. ZrO2 nanoparticles confined in CMK-3 as highly effective sorbent for phosphate adsorption. Microporous Mesoporous Mater 2016; 230: 188-95.
[15]
Bhatnagar A, Sillanpa M, Krowiak AW. Agricultural waste peels as versatile biomass for water purification - A review. Chem Eng J 2015; 270: 244-71.
[16]
Gautam RK, Mudhoo A, Lofrano G, Chattopadhyaya MC. Biomass-derived biosorbents for metal ions sequestration: Adsorbent modification and activation methods and adsorbent regeneration. J Environ Chem Eng 2014; 2: 239-59.
[17]
Li X, Xu T, Xu P, Yu H, Guo S. Use of mesoporous silica nanomaterials for adsorption and degradation of organophosphorus pesticides Chinese Patent 104771857, 2015.
[18]
Chen Z, Chen B, Lv S. A novel magnetic biochar efficiently sorbs organic pollutants and phosphate. Bioresour Technol 2011; 102: 716-23.
[19]
Gong J, Long F, Zeng G, et al. Removal of phosphate from aqueous solution by magnetic Fe-Zr binary oxide. Chem Eng J 2011; 171: 448-55.
[20]
Patra BS, Das J, Baliarsingh N, Parida KM. Adsorption of phosphate by layered double hydroxides in aqueous solutions. Appl Clay Sci 2006; 32: 252-60.
[21]
Gao B, Yao Y, Inyang M, et al. Removal of phosphate from aqueous solution by biochar derived from anaerobically digested sugar beet tailings. J Hazard Mater 2011; 190: 501-7.
[22]
Chen N, Gao Y, Hu W, et al. Phosphate removal from aqueous solution by an effective clay composite material. J Solution Chem 2013; 42: 691-704.
[23]
Ahmed OE, Khalil ME, Amen TWM, Sugihara Y, Matsuna N. Optimized nano-scale zero-valent iron supported on treated activated carbon for enhanced nitrate and phosphate removal from water. Chem Eng J 2016; 309: 349-65.
[24]
Zhan Y, Lin J, Wang H, et al. Effect of calcium ion on phosphate adsorption onto hydrous zirconium oxide. Chem Eng J 2016; 309: 118-29.
[25]
Devi P, Saroha AK. Utilization of sludge based adsorbents for the removal of various pollutants: A review. Sci Total Environ 2017; 578: 16-33.
[26]
Orozco NT, Cabrera RI, Tecante A, Gimeno M, Parra R, Arrazola RG. Removal strategies for endocrine disrupting chemicals using cellulose-based materials as adsorbents: A review. J Environ Chem Eng 2016; 4: 3122-42.
[27]
Anastopoulos I, Bhatnagar A, Hameed BH, Ok YS, Omirou M. A review on waste-derived adsorbents from sugar industry for pollutant removal in water and wastewater. J Mol Liq 2017; 240: 179-88.
[28]
Xu G, Yang X, Spinosa L. Development of sludge-based adsorbents: Preparation, characterization, utilization and its feasibility assessment. J Environ Manage 2015; 151: 221-32.
[29]
Su C. Environmental implications and applications of engineered nanoscalemagnetite and its hybrid nanocomposites: A review of recent literature. J Hazard Mater 2016; 322: 48-84.
[30]
Zhang S, Hua M, Pan B, Zhang W, Lv L, Zhang Q. Heavy metal removal from water/wastewater by nanosized metal oxides: A review. J Hazard Mater 2012; 317-31.
[31]
Fakhru’l-Razi A, Pendashteh A, Abdullah LC, et al. Review of technologies for oil and gas produced water treatment. J Hazard Mater 2009; 170: 530-51.
[32]
Hasan Z, Khan NA, Jhung SH. Adsorptive removal of hazardous materials using Metal-Organic Frameworks (MOFs): A review. J Hazard Mater 2013; 244-245: 444-56.
[33]
Baliarsingh N, Parida KM, Pradhan GC. Influence of the nature and concentration of precursor metal ions in the brucite layer of LDHs for phosphate adsorption - A review. RSC Advances 2013; 3: 23865-78.
[34]
Li D, Qian L, Feng Y, Feng J, Tang P, Yang L. Co-intercalation of acid red 337 and a UV absorbent into layered double hydroxides: Enhancement of photostability. ACS Appl Mater Interfaces 2014; 6: 20603-11.
[35]
Chi J, Yu H, Qin B, et al. Vertically aligned FeOOH/NiFe layered double hydroxides electrode for highly efficient oxygen evolution reaction. ACS Appl Mater Interfaces 2017; 9: 464-71.
[36]
Wei Y, Chen S, Li F, Lin Y, Zhang Y, Liu L. Highly stable and sensitive paper-based bending sensor using silver nanowires/ layered double hydroxides hybrids. ACS Appl Mater Interfaces 2015; 7: 14182-91.
[37]
Abellán G, Gastaldo CM, Ribera A, Coronado E. Hybrid materials based on magnetic layered double hydroxides: A molecular perspective. Acc Chem Res 2015; 48: 1601-11.
[38]
Gong J, Liu T, Wang X, Hu X, Zhang L. Efficient removal of heavy metal ions from aqueous systems with the assembly of anisotropic layered double hydroxide Nanocrystals@carbon nanosphere. Environ Sci Technol 2011; 45: 6181-7.
[39]
Zhang X, Guo L, Huang H, Jiang Y, Li M, Leng Y. Removal of phosphorus by the core-shell bio-ceramic/Zn-Layered Double Hydroxides (LDHs) composites for municipal wastewater treatment in constructed rapid infiltration system. Water Res 2016; 96: 280-91.
[40]
Ma L, Wang Q, Islam SM, Liu Y, Ma S, Kanatzidis MG. Highly selective and efficient removal of heavy metals by layered double hydroxide intercalated with the MoS42– Ion. J Am Chem Soc 2016; 138: 2858-66.
[41]
Yan L, Yang K, Shan R, et al. Kinetic, isotherm and thermodynamic investigations of phosphate adsorption onto core-shell Fe3O4@LDHs composites with easy magnetic separation assistance. J Colloid Interface Sci 2015; 448: 508-16.
[42]
Everaert M, Warrinnier R, Baken S, Gustafsson JP, Vos DD, Smolders E. Phosphate-exchanged Mg-Al layered double hydroxides: A new slow release phosphate fertilizer. ACS Sustain Chem& Eng 2016; 4: 4280-7.
[43]
He J, Wang W, Sun F, et al. Highly efficient phosphate scavenger based on well-dispersed La(OH)3 nanorods in polyacrylonitrile nanofibers for nutrient-starvation antibacteria. ACS Nano 2015; 9: 9292-302.
[44]
Mahaninia MH, Wilson LD. Phosphate uptake studies of cross-linked chitosan bead materials. J Colloid Interface Sci 2017; 485: 201-12.
[45]
Chen T, Zhang Y, Yang X, Tang Y. Preparation of phosphorus adsorption composite material by stripping zinc aluminum layered double hydroxide to obtain stripped zinc aluminum layered double hydroxide colloidal solution, and adding with macromolecule solution Chinese Patent 102441365, 2012
[46]
Fan G, Li F, Evans DG, Duan X. Catalytic applications of layered double hydroxides: Recent advances and perspectives. Chem Soc Rev 2014; 43: 7040-66.
[47]
Zhang M, Gao B, Fang J, Creamer AE, Ullman JL. Self-assembly of needle-like Layered Double Hydroxide (LDH) nanocrystals on hydrochar: Characterization and phosphate removal ability. RSC Advances 2014; 4: 28171-5.
[48]
Li R, Wang JJ, Zhou B, et al. Enhancing phosphate adsorption by Mg/Al layered double hydroxide functionalized biochar with different Mg/Al ratios. Sci Total Environ 2016; 559: 121-9.
[49]
Jia Y, Wang H, Zhao X, et al. Kinetics, isotherms and multiple mechanisms of the removal for phosphate by Cl-hydrocalumite. Appl Clay Sci 2016; 129: 116-21.
[50]
Novillo C, Guaya D, Avendaño AAP, Armijos C, Cortina JL, Cota I. Evaluation of phosphate removal capacity of Mg/Al layered double hydroxides from aqueous solutions. Fuel 2014; 138: 72-9.
[51]
Weber WJ. Procedding of international conferene on water pollution symposium Pergamon Oxford 1962; 2: 231-66
[52]
Cai P, Zheng H, Wang C, et al. Competitive adsorption characteristics of fluoride and phosphate on calcined Mg-Al-CO3 layered double hydroxides. J Hazard Mater 2012; 213-214: 100-8.
[53]
Zhan T, Zhang Y, Yang Q, Deng H, Xu J, Hou W. Ultrathin layered double hydroxide nanosheets prepared from a water-in-ionic liquid surfactant-free microemulsion for phosphate removal from aquatic systems. Chem Eng J 2016; 302: 459-65.
[54]
Halajnia H, Najafi ON, Khataee AR, Lakzian A. Adsorption-desorption characteristics of nitrate, phosphate and sulfate on Mg-Al layered double hydroxide. Appl Clay Sci 2013; 80-81: 305-12.
[55]
Koilraj P, Sasaki K. Fe3O4/MgAl-NO3 layered double hydroxide as a magnetically separable sorbent for the remediation of aqueous phosphate. J Environ Chem Eng 2016; 4: 984-91.
[56]
Zhou J, Yang S, Yu J, Shu Z. Novel hollow microspheres of hierarchical zinc-aluminum layered double hydroxides and their enhanced adsorption capacity for phosphate in water. J Hazard Mater 2011; 192: 1114-21.
[57]
Cheng X, Huang X, Wang X, Sun D. Influence of calcination on the adsorptive removal of phosphate by Zn-Al layered double hydroxides from excess sludge liquor. J Hazard Mater 2010; 177: 516-23.
[58]
Cheng X, Ye J, Sun D, Chen A. Influence of synthesis temperature on phosphate adsorption by Zn-Al Layered double hydroxides in excess sludge liquor. Chin J Chem Eng 2011; 19: 391-6.
[59]
He H, Kang H, Ma S, Bai Y, Yang X. High adsorption selectivity of ZnAl layered double hydroxides and the calcined materials toward phosphate. J Colloid Interface Sci 2010; 343: 225-31.
[60]
Yu Q, Zheng Y, Wang Y, et al. Highly selective adsorption of phosphate by pyromellitic acid intercalated ZnAl-LDHs: Assembling hydrogen bond acceptor sites. Chem Eng J 2015; 260: 809-17.
[61]
Sun X, Imai T, Sekine M, et al. Adsorption of phosphate using calcined Mg3-Fe layered double hydroxides in a fixed-bed column study. J Ind Eng Chem 2014; 20: 3623-30.
[62]
Wang X, Liu F, Lu L, et al. Individual and competitive adsorption of Cr(VI) and phosphate onto synthetic Fe-Al hydroxides. Colloids Surf A 2013; 423: 42-9.
[63]
Tuhtan AD, Schneider M, Mandel K, et al. Influence of cation building blocks of metal hydroxide precipitates on their adsorption and desorption capacity for phosphate in wastewater-A screening study. Colloid Surf A 2016; 488: 145-53.
[64]
Ashekuzzaman SM, Jiang J. Study on the sorption-desorption-regeneration performance of Ca-, Mg- and CaMg-based layered double hydroxides for removing phosphate from water. Chem Eng J 2014; 246: 97-105.
[65]
Kim M, Kim H, Byeon S. Layered yttrium hydroxide l-Y(OH)3 luminescent adsorbent for detection and recovery of phosphate from water over a wide pH range. ACS Appl Mater Interfaces 2017; 9: 40461-70.
[66]
Koilraj P, Kannan S. Phosphate uptake behavior of ZnAlZr ternary layered double hydroxides through surface precipitation. J Colloid Interface Sci 2010; 341: 289-97.
[67]
Park J, Wang JJ, Xiao R, Zhou B, Delaune RD, Seo D. Effect of pyrolysis temperature on phosphate adsorption characteristics and mechanisms of crawfish char. J Colloid Interface Sci 2018; 525: 143-51.
[68]
Hua G, Salo MW, Schmit CG, Hay CH. Nitrate and phosphate removal from agricultural subsurface drainage using laboratory woodchip bioreactors and recycled steel byproduct filters. Water Res 2016; 102: 180-9.
[69]
Qiu H, Liang C, Zhang X, et al. Fabrication of a biomass-based hydrous zirconium oxide nanocomposite for preferable phosphate removal and recovery. ACS Appl Mater Interfaces 2015; 7: 20835-44.
[70]
Zhang Y, Liu F, Zhu C, et al. Multifold enhanced synergistic removal of nickel and phosphate by a (N,Fe)-dual-functional bio-sorbent: Mechanism and application. J Hazard Mater 2017; 329: 290-8.
[71]
Wang J, Tong X, He D. Preparation of zirconium-modified sludge adsorbent used for removing phosphate in water involves adding chloroacetic acid to activated sludge powder, washing with water, reacting with zirconium sulfate tetrahydrate, and freeze-drying Chinese Patent 106669620, 2017
[72]
Lee KS, Min K. Shell meal used as bio-waste resource for adsorption and removal of various pigments, includes phosphorus powder and biological waste resource Korean Patent 2017025687, 2017.
[73]
Qin F, Shen W, Sun W, et al. Preparing modified zeolite adsorbing
agent useful for removing ammonia nitrogen and phosphate in water,
comprises e.g. screening and milling natural zeolite, subjecting
to ultrasonic condition and carrying out hydrothermal treatment.
Chinese Patent 105381782, 2016
[74]
Lian J, Chen B, Jia Y, Meng H, Sheng G, Liu Z. Preparation of bio-carbon composite adsorbent material used for removing phosphate from surface water, involves drying grapefruit skin, and orange peel to obtain biomass solid, heating, cooling, and adding into ferric sulfate solution Chinese Patent 106390927, 2017
[75]
Sang HL, Jae WC, Byung RA, Chan HP, Kyu SK, Soon JL. Filter unit used for removing phosphate and arsenic in water, comprises cover, which is provided with fluid inlet tube in center of cover, and filter unit comprises filter cartridge housing Korean Patent
2016103344, 2016
[76]
Malmborg C, Meinander N. Use of a chitosan adsorbent complexed
with a metal ion for simultaneous adsorption of urea and phosphate
from a dialysis fluid, where the metal ion is copper(II) bound to
chitosan. US Patent 2015273131-A1 2015
[77]
Liu J, Zhang H, Zhang P, et al. Preparation of red mud adsorbent particles involves mixing activated red mud and straw powder with hydroxypropylmethylcellulose, obtaining granulated molded product, calcining and mixing obtained adsorbent with phosphate solution Chinese Patent 104888686, 2015
[78]
Dong Z, Li Y, Qiu Y, Shi K. Usage method of activated carbon for adsorption of phosphate ions in liquid, involves adding ionic liquid to phosphate-containing liquid, mixing, adding activated carbon, adsorbing, eluting, adjusting pH and recycling activated carbon Chinese Patent 105399179, 2016
[79]
Guo X, Wang B, Zhang P, et al. Moveable prying-type phosphating waste water processing device comprises adsorption tank, sedimentation tank and neutralizing tank, where adsorption tank comprises activated carbon adsorbent inlet and waste water inlet Chinese Patent 205567038, 2016
[80]
Liu S, Tan X, Liu Y, et al. Production of biochars from Ca impregnated ramie biomass (Boehmeria nivea (L.) Gaud.) and their phosphate removal potential. RSC Advances 2016; 6: 5871-80.
[81]
Wan S, Wu J, He F, et al. Phosphate removal by lead-exhausted bioadsorbents simultaneously achieving lead stabilization. Chemosphere 2017; 168: 748-55.
[82]
Jiang Y, Deng T, Yang K, Wang H. Removal performance of phosphate from aqueous solution using a high-capacity sewage sludge-based adsorbent. J Taiwan Inst Chem Eng 2016; 76: 59-64.
[83]
Luo X, Liu C, Yuan J, Zhu X, Liu S. Interfacial solid-phase chemical modification with mannich reaction and Fe(III) chelation for designing lignin-based spherical nanoparticle adsorbents for highly efficient removal of low concentration phosphate from water. ACS Sustain Chem& Eng 2017; 5: 6539-47.
[84]
Wajima T, Rakovan JF. Removal behavior of phosphate from aqueous solution by calcined paper sludge. Colloid Surf A 2013; 435: 132-8.
[85]
Zhao Y, Yue Q, Li Q, et al. Characterization of Red Mud Granular Adsorbent (RMGA) and its performance on phosphate removal from aqueous solution. Chem Eng J 2012; 193-194: 161-8.
[86]
Rubio-Rincón FJ, Lopez-Vazquez CM, Welles L, Loosdrecht MCMV, Brdjanovic D. Cooperation between candidatus competibacter and candidatus accumulibacter clade I, in denitrification and phosphate removal processes. Water Res 2017; 120: 156-64.
[87]
Sevcenco A, Paravidino M, Vrouwenvelder JS, Wolterbeek HT, Loosdrecht MCMV, Hagen WR. Phosphate and arsenate removal efficiency by thermostable ferritin enzyme from Pyrococcus furiosus using radioisotopes. Water Res 2015; 76: 181-6.
[88]
Seliem MK, Komarneni S, Khadra MRA. Phosphate removal from solution by composite of MCM-41 silica with rice husk: Kinetic and equilibrium studies. Microporous Mesoporous Mater 2016; 224: 51-7.
[89]
Benammar L, Menasria T, Ayachi A, Benounis M. Phosphate removal using aerobic bacterial consortium and pure cultures isolated from activated sludge. Process Saf Environ Prot 2015; 95: 237-46.
[90]
Lalley J, Han C, Li X, Dionysiou DD, Nadagouda MN. Phosphate adsorption using modified iron oxide-based sorbents in lake water: Kinetics, equilibrium, and column tests. Chem Eng J 2016; 284: 1386-96.
[91]
Deng H, Chen Y, Cao Y, Chen W. Enhanced phosphate and fluoride removal from aqueous solution by ferric-modified chromium (III)-fibrous protein. J Taiwan Inst Chem Eng 2016; 68: 323-31.
[92]
Hermassi M, Valderrama C, Moreno N, et al. Fly ash as reactive sorbent for phosphate removal from treated waste water as a potential slow release fertilizer. J Environ Chem Eng 2017; 5: 160-9.
[93]
Kumar IA, Viswanathan N. Fabrication of metal ions cross-linked alginate assisted biocomposite beads for selective phosphate removal. J Environ Chem Eng 2017; 5: 1438-46.
[94]
Zhao T, Feng T. Application of modified chitosan microspheres for nitrate and phosphate adsorption from aqueous solution. RSC Advances 2016; 6: 90878-86.
[95]
Wang T, Xu X, Ren Z, Gao B, Wang H. Adsorption of phosphate on surface of magnetic reed: characteristics, kinetic, isotherm, desorption, competitive and mechanistic studies. RSC Advances 2016; 6: 5089-99.
[96]
Rajeswari A, Amalraj A, Pius A. Removal of phosphate using chitosan-polymer composites. J Environ Chem Eng 2015; 3: 2331-41.
[97]
Chen D, Xiao X, Yang K. Removal of phosphate and hexavalent chromium from aqueous solutions by engineered waste eggshell. RSC Advances 2016; 6: 35332-9.
[98]
Wang Z, Fan Y, Li Y, Qu F, Wu D, Kong H. Synthesis of zeolite/hydrous lanthanum oxide composite from coal fly ash for efficient phosphate removal from lake water. Microporous Mesoporous Mater 2016; 222: 226-34.
[99]
Ren Z, Xu X, Wang X, et al. FTIR, Raman, and XPS analysis during phosphate, nitrate and Cr(VI) removal by amine cross-linking biosorbent. J Colloid Interface Sci 2016; 468: 313-23.
[100]
Jung K, Jeong T, Kang H, Ahn K. Characteristics of biochar derived from marine macroalgae and fabrication of granular biochar by entrapment in calcium-alginate beads for phosphate removal from aqueous solution. Bioresour Technol 2016; 211: 108-16.
[101]
Arshadi M, Gholtash JE, Zandi H, Foroughifard S. Phosphate removal by a nano-biosorbent from the synthetic and real (Persian Gulf) water samples. RSC Advances 2015; 5: 43290-302.
[102]
Wang H, Wang X, Xia P, et al. Eco-friendly synthesis of self-existed magnesium oxide supported nanorod-like palygorskite for enhanced and simultaneous recovery of nutrients from simulated wastewater through adsorption and in situ struvite formation. Appl Clay Sci 2017; 135: 418-26.
[103]
Ahmed S, Guo Y, Li D, Tang P, Feng Y. Superb removal capacity of hierarchically porous magnesium oxide for phosphate and methyl orange. Environ Sci Pollut Res 2018; 25: 24907-16.
[104]
Cao D, Jin X, Gan L, Wang T, Chen Z. Removal of phosphate using iron oxide nanoparticles synthesized by eucalyptus leaf extract in the presence of CTAB surfactant. Chemosphere 2016; 159: 23-31.
[105]
Gu W, Xie Q, Qi C, Zhao L, Wu D. Phosphate removal using zinc ferrite synthesized through a facile solvothermal technique. Powder Technol 2016; 301: 723-9.
[106]
Mohamed RM, Shawky A, Mkhalid IA. Facile synthesis of MgO and Ni-MgO nanostructures with enhanced adsorption of methyl blue dye. J Phys Chem Solids 2017; 101: 50-7.
[107]
Chen L, Zhao X, Pan B, et al. Preferable removal of phosphate from water using hydrous zirconium oxide-based nanocomposite of high stability. J Hazard Mater 2015; 284: 35-42.
[108]
Purwajanti S, Zhou L, Nor YA, et al. Synthesis of magnesium oxide hierarchical microspheres: A dual-functional material for water remediation. ACS Appl Mater Interfaces 2015; 7: 21278-86.
[109]
Huang R, He L, Zhang T, Li D, Tang P, Feng Y. Novel carbon paper@magnesium silicate composite porous films: Design, fabrication, and adsorption behavior for heavy metal ions in aqueous solution. ACS Appl Mater Interfaces 2018; 10: 22776-85.
[110]
Huang R, Wu M, Zhang T, Li D, Tang P, Feng Y. Template-free synthesis of large-pore-size porous magnesium silicate hierarchical nanostructures for high-efficiency removal of heavy metal ions. ACS Sustain Chem& Eng 2017; 5: 2774-80.
[111]
Sleiman N, Deluchat V, Wazne M, et al. Phosphate removal from aqueous solutions using Zero Valent Iron (ZVI): Influence of solution composition and ZVI aging. Colloids Surf A 2017; 514: 1-10.
[112]
Lin B, Hua M, Zhang Y, Zhang W, Lv L, Pan B. Effects of organic acids of different molecular size on phosphate removal by HZO-201 nanocomposite. Chemosphere 2017; 166: 422-30.
[113]
Ahmed S, Ashiq MN, Li D, Tang P, Feng Y. Carbon fiber paper@MgO films: In situ fabrication and high-performance removal capacity for phosphate anions. Environ Sci Pollut Res 2018; 25: 34788-92.
[114]
Qiang T, Zhao J, Ren L. Preparation of zirconium-mesoporous material for use in adsorption of phosphate ions in water, involves dissolving tri-block copolymer template of polyethylene glycol-polypropylene glycol-polyethylene glycol in alcohol-water mixed solution . Chinese Patent 106475078, 2017
[115]
Chen S, Shen M, Chen X, Li C, Qiu C. Zirconium hydroxide for adsorbing phosphate, is prepared by alkaline hydrolysis of zinc salt Chinese Patent 105435733, 2012.
[116]
Wang Y, Zhou R. Adsorption of phosphate pollutants in wastewater, involves drying copper tailings, grinding, sieving, drying, calcining copper tailings, thermally modifying, placing modified copper tailings in phosphate solution Chinese Patent 107032439,
2017
[117]
Ge X, Song X, Ma Y, et al. Fabrication of hierarchical iron-containing MnO2 hollow microspheres assembled by thickness-tunable nanosheets for efficient phosphate removal. J Mater Chem A 2016; 4: 14814-26.
[118]
Xu D, Hu Y, Wang Z, et al. Removal of phosphate on water by adsorption on cerium oxide-modified iron oxide silicon dioxide magnetic nanoparticles involves using cerium oxide-modified iron oxide silicon dioxide magnetic nanoparticles as adsorbent Chinese
Patent 103964538, 2014
[119]
Liu F, Yang B, Wang P, Zuo J, Xie B. Efficient nanoiron-loaded material used for adsorption of phosphate in water, comprises graphene and nanoiron Chinese patent 103011328, 2013
[120]
Besemer AC, Calderone VR, Duin RJV. Removing phosphate from
phosphate-containing water fraction comprises contacting the fraction
with an adsorbent, where the adsorbent comprises a complex
of ferric and starch, and withdrawing an effluent water fraction
from the adsorbent. WO 2015181205, 2015
[121]
Huang Y, Pan J, Wang C, Yan Y, Zheng X. Preparation of nano-structure composite adsorption material for adsorbing and separating phosphate ions in wastewater, involves immersing mesoporous silica membrane material in ethanol, adding lanthanum nitrate crystals, and calcining Chinese Patent 104667882, 2015
[122]
Hirokawa T, Noishiki T, Kimura N, Amaike M. Method for adsorbing
target anions e.g. phosphate ions from wastewater, involves
passing water containing anions and having preset pH through adsorption
apparatus filled with anion adsorbent comprising iron
oxyhydroxide. Japanese Patent 2017544200, 2017
[123]
Wang C, Zheng X, Zhang F, Huang Y, Pan J. A novel Fe-La-doped hierarchical porous silica magnetic adsorbent for phosphate removal. RSC Advances 2016; 6: 87808-19.
[124]
Chen M, Huo C, Li Y, Wang J. Selective adsorption and efficient removal of phosphate from aqueous medium with graphene-lanthanum composite. ACS Sustain Chem& Eng 2016; 4: 1296-302.
[125]
Mitrogiannis D, Psychoyou M, Baziotis I, et al. Removal of phosphate from aqueous solutions by adsorption onto Ca(OH)2 treated natural clinoptilolite. Chem Eng J 2017; 320: 510-22.
[126]
Pan M, Lin X, Xie J, Huang X. Kinetic, equilibrium and thermodynamic studies for phosphate adsorption on aluminum hydroxide modified palygorskite nano-composites. RSC Advances 2017; 7: 4492-500.
[127]
Jeyong Y, Choonsoo K. Adsorbent useful for selectively adsorbing arsenic and phosphate, comprises ion-bonded form metal ions and molybdenum provided on strong anion exchanger resin Korean
Patent 1768803, 2017
[128]
Liu H, Guo W, Liu Z, Li X, Wang R. Effective adsorption of phosphate from aqueous solution by La-based metal-organic frameworks. RSC Advances 2016; 6: 105282-7.
[129]
Yang J, Zhou L, Zhao L, et al. A designed nanoporous material for phosphate removal with high efficiency. J Mater Chem 2011; 21: 2489-94.
[130]
Du X, Han Q, Li J, Li H. The behavior of phosphate adsorption and its reactions on the surfaces of Fe-Mn oxide adsorbent. J Taiwan Instit Chem Eng 2017; 76: 167-75.
[131]
Zhou J, Yang S, Yu J. Facile fabrication of mesoporous MgO microspheres and their enhanced adsorption performance for phosphate from aqueous solutions. Colloids Surf A 2011; 379: 102-8.
[132]
Yang J, Yuan P, Chen H, Zou J, Yuan Z, Yu C. Rationally designed functional macroporous materials as new adsorbents for efficient phosphorus removal. J Mater Chem 2012; 22: 9983-90.
[133]
He Y, Lin H, Dong Y, Wang L. Preferable adsorption of phosphate using lanthanum-incorporated porous zeolite: Characteristics and mechanism. Appl Surf Sci 2017; 426: 995-1004.
[134]
Zhang Y, Pan B, Shan C, Gao X. Enhanced phosphate removal by nanosized hydrated La(III) oxide confined in cross-linked polystyrene networks. Environ Sci Technol 2016; 50: 1447-54.
[135]
Xie J, Wang Z, Fang D, Li C, Wu D. Green synthesis of a novel hybrid sorbent of zeolite/lanthanum hydroxide and its application in the removal and recovery of phosphate from water. J Colloid Interface Sci 2014; 423: 13-9.
[136]
Yu Y, Chen JP. Key factors for optimum performance in phosphate removal from contaminated water by a Fe-Mg-La tri-metal composite sorbent. J Colloid Interface Sci 2015; 445: 303-11.
[137]
Huang Y, Yang J, Keller AA. Removal of arsenic and phosphate from aqueous solution by metal (Hydr-)oxide coated sand. ACS Sustain Chem& Eng 2014; 2: 1128-38.
[138]
Zong E, Wei D, Wan H, Zheng S, Xu Z, Zhu D. Adsorptive removal of phosphate ions from aqueous solution using zirconia-functionalized graphite oxide. Chem Eng J 2013; 221: 193-203.
[139]
Qin K, Li F, Xu S, Wang T, Liu C. Sequential removal of phosphate and cesium by using zirconium oxide: A demonstration of designing sustainable adsorbents for green water treatment. Chem Eng J 2017; 322: 275-80.
[140]
Wang S, Ma M, Man W, et al. One-step facile fabrication of sea urchin-like zirconium oxide for efficient phosphate sequestration. RSC Advances 2015; 5: 91218-24.
[141]
Schneider M, Drenkova-Tuhtan A, Szczerba W, et al. Nanostructured ZnFeZr oxyhydroxide precipitate as efficient phosphate adsorber in waste water: understanding the role of different material-building-blocks. Environ Sci Nano 2017; 4: 180-90.
[142]
Emmanuelawati I, Yang J, Zhang J, Zhang H, Zhou L, Yu C. Low-cost and large-scale synthesis of functional porous materials for phosphate removal with high performance. Nanoscale 2013; 5: 6173-80.
[143]
Huang W, Zhu Y, Tang J, et al. Lanthanum-doped ordered mesoporous hollow silica spheres as novel adsorbents for efficient phosphate removal. J Mater Chem A 2014; 2: 8839-48.
[144]
Wang Y, Lu H, Liu Y, Yang S. Removal of phosphate from aqueous solution by SiO2-biochar nanocomposites prepared by pyrolysis of vermiculite treated algal biomass. RSC Advances 2016; 6: 83534-46.
[145]
Zhang Q, Teng J, Zou G, et al. Efficient phosphate sequestration for water purification by unique sandwich-like MXene/magnetic iron oxide nanocomposites. Nanoscale 2016; 8: 7085-93.
[146]
Sarkar A, Biswas SK, Pramanik P. Design of a new nanostructure comprising mesoporous ZrO2 shell and magnetite core (Fe3O4@mZrO2) and study of its phosphate ion separation efficiency. J Mater Chem 2010; 20: 4417-24.
[147]
Wang W, Zhang H, Zhang L, Wan H, Zheng S, Xu Z. Adsorptive removal of phosphate by magnetic Fe3O4@C@ZrO2. Colloids Surf A 2015; 469: 100-6.
[148]
Wu B, Fang L, Fortner JD, Guan X, Lo IMC. Highly efficient and selective phosphate removal from wastewater by magnetically recoverable La(OH)3/Fe3O4 nanocomposites. Water Res 2017; 126: 179-88.
[149]
Wang H, Zhang P, Liu J. Triethylene tetramine functionalized magnetic graphene oxide chitosan composite with superior capacity for the removal of phosphate. J Chem Eng Data 2017; 62: 3341-52.
[150]
Rout PR, Bhunia P, Dash RR. Effective utilization of a sponge iron industry by-product for phosphate removal from aqueous solution: A statistical and kinetic modelling approach. J Taiwan Instit Chem Eng 2015; 46: 98-108.
[151]
Harijan DKL, Chandra V. Akaganeite nanorods decorated graphene oxide sheets for removal and recovery of aqueous phosphate. J Water Process Eng 2017; 19: 120-5.
[152]
Shen H, Wang Z, Zhou A, et al. Adsorption of phosphate onto amine functionalized nano-sized magnetic polymer adsorbents: mechanism and magnetic effects. RSC Advances 2015; 5: 22080-90.
[153]
Tran DNH, Kabiri S, Wang L, Losic D. Engineered graphene-nanoparticle aerogel composites for efficient removal of phosphate from water. J Mater Chem A 2015; 3: 6844-52.
[154]
Sleiman N, Deluchat V, Wazne M, et al. Role of iron oxidation byproducts in the removal of phosphate from aqueous solution. RSC Advances 2016; 6: 1627-36.
[155]
Ye Y, Hu Y, Hussain Z, Li Z, Li D, Kang J. Simultaneous adsorptive removal of fluoride and phosphate by magnesia-pullulan composite from aqueous solution. RSC Advances 2016; 6: 35966-76.
[156]
Pan B, Han F, Nie G, Wu B, He K, Lu L. New strategy to enhance phosphate removal from water by hydrous manganese oxide. Environ Sci Technol 2014; 48: 5101-7.
[157]
Kuwahara Y, Ohmichi T, Kamegawa T, Mori K, Yamashita H. A novel conversion process for waste slag: synthesis of a hydrotalcite-like compound and zeolite from blast furnace slag and evaluation of adsorption capacities. J Mater Chem 2010; 20: 5052-62.
[158]
Kuokkanen V, Kuokkanen T, Rämö J, Lassi U, Roininen J. Removal of phosphate from wastewaters for further utilization using electrocoagulation with hybrid electrodes - Techno-economic studies. J Water Process Eng 2015; 8: 50-7.
[159]
Park J, Wang JJ, Kim S, et al. Phosphate removal in constructed wetland with rapid cooled basic oxygen furnace slag. Chem Eng J 2017; 327: 713-24.
[160]
Han B, Chen N, Deng D, Deng S, Djerdj I, Wang H. Enhancing phosphate removal from water by using ordered mesoporous silica loaded with samarium oxide. Anal Methods 2015; 7: 10052-60.
[161]
Xie J, Lin Y, Li C, Wu D, Kong H. Removal and recovery of phosphate from water by activated aluminum oxide and lanthanum oxide. Powder Technol 2015; 269: 351-7.
Related Books
The Art of Nanomaterials
Advanced Materials and Nano Systems: Theory and Experiment - Part 2
Advanced Materials and Nano Systems: Theory and Experiment (Part-1)
Artificial Intelligence for Smart Cities and Villages: Advanced Technologies, Development, and Challenges
SILVER NANOPARTICLES: Synthesis, Functionalization and Applications
Article Metrics
106
19
1