Synthesis of Asymmetric Diaryl Sulfides by SNAr Reaction of Substituted Nitrobenzene with Aryl Disulfides

Naoki      Enjo; Rong      Lu; Tetsuo      Miyakoshi

doi:10.2174/157017941006140206105221

Abstract

A series of sulfides was successfully synthesized from nitroarenes by S_NAr reaction via elimination of a nitro or phenylsulfonyl group. The S_NAr reaction mechanism is found to depend on the position and type of substituents, and the effect of two-electron withdrawing groups was also examined.

Keywords: Sulfide, S_NAr reaction, nitro group, aryl disulfide.

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Current Organic Synthesis

Title:Synthesis of Asymmetric Diaryl Sulfides by S_NAr Reaction of Substituted Nitrobenzene with Aryl Disulfides

Volume: 10 Issue: 6

Author(s): Naoki Enjo, Rong Lu and Tetsuo Miyakoshi

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Keywords: Sulfide, S_NAr reaction, nitro group, aryl disulfide.

Abstract: A series of sulfides was successfully synthesized from nitroarenes by S_NAr reaction via elimination of a nitro or phenylsulfonyl group. The S_NAr reaction mechanism is found to depend on the position and type of substituents, and the effect of two-electron withdrawing groups was also examined.

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Enjo Naoki, Lu Rong and Miyakoshi Tetsuo, Synthesis of Asymmetric Diaryl Sulfides by S_NAr Reaction of Substituted Nitrobenzene with Aryl Disulfides, Current Organic Synthesis 2013; 10 (6) . https://dx.doi.org/10.2174/157017941006140206105221

DOI https://dx.doi.org/10.2174/157017941006140206105221	Print ISSN 1570-1794
Publisher Name Bentham Science Publisher	Online ISSN 1875-6271