Three Component Mannich Reaction and 1,5-Benzodiazepine Synthesis Catalyzed by a Tetranitrile-Silver Complex

Gopalakrishnapanicker   Rajesh   Krishnan; Radhakrishnan      Sreerekha; Krishnapillai      Sreekumar

doi:10.2174/157017809787003188

Abstract

This manuscript describes the first example of silver ion complex of a dendritic tetranitrile ligand catalyzed one-pot three component Mannich reaction and 1,5-benzodiazepine synthesis. The catalyst can be separated from the products by a change in the solvent. The catalyst is reusable.

Keywords: Homogeneous catalysis, tetranitrile, silver complex, Mannich reaction, 2-aminoketones, 1,5 benzodiazepine

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Letters in Organic Chemistry

Title: Three Component Mannich Reaction and 1,5-Benzodiazepine Synthesis Catalyzed by a Tetranitrile-Silver Complex

Volume: 6 Issue: 1

Author(s): Gopalakrishnapanicker Rajesh Krishnan, Radhakrishnan Sreerekha and Krishnapillai Sreekumar

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Keywords: Homogeneous catalysis, tetranitrile, silver complex, Mannich reaction, 2-aminoketones, 1,5 benzodiazepine

Abstract: This manuscript describes the first example of silver ion complex of a dendritic tetranitrile ligand catalyzed one-pot three component Mannich reaction and 1,5-benzodiazepine synthesis. The catalyst can be separated from the products by a change in the solvent. The catalyst is reusable.

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Krishnan Rajesh Gopalakrishnapanicker, Sreerekha Radhakrishnan and Sreekumar Krishnapillai, Three Component Mannich Reaction and 1,5-Benzodiazepine Synthesis Catalyzed by a Tetranitrile-Silver Complex, Letters in Organic Chemistry 2009; 6 (1) . https://dx.doi.org/10.2174/157017809787003188