An Intriguing, Regioselective Synthesis of Novel 2-(1-Adamantylmethyl) tetrahydropyridines

George   B.   Foscolos; Ioannis      Papanastasiou; Andrew      Tsotinis

doi:10.2174/157017808783330117

Abstract

Treatment of piperidine 8 with acetyl chloride or ethyl chloroformate in the presence of triethylamine gave the 2,3-dehydrogenated products 10a and 10b, respectively, together with the expected N-acylpiperidines 9.

Keywords: N-acyl adamantylmethylpiperidines, N-acyl adamantylmethyltetrahydropiperidines, synthesis

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Letters in Organic Chemistry

Title: An Intriguing, Regioselective Synthesis of Novel 2-(1-Adamantylmethyl) tetrahydropyridines

Volume: 5 Issue: 1

Author(s): George B. Foscolos, Ioannis Papanastasiou and Andrew Tsotinis

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Keywords: N-acyl adamantylmethylpiperidines, N-acyl adamantylmethyltetrahydropiperidines, synthesis

Abstract: Treatment of piperidine 8 with acetyl chloride or ethyl chloroformate in the presence of triethylamine gave the 2,3-dehydrogenated products 10a and 10b, respectively, together with the expected N-acylpiperidines 9.

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Foscolos B. George, Papanastasiou Ioannis and Tsotinis Andrew, An Intriguing, Regioselective Synthesis of Novel 2-(1-Adamantylmethyl) tetrahydropyridines, Letters in Organic Chemistry 2008; 5 (1) . https://dx.doi.org/10.2174/157017808783330117