Abstract
A series of novel chiral di-imidazolium tweezers were synthesized from L-alanine and L-phenylalanine. These compounds featured two open arms and multipoint binding sites. UV spectroscopic titration experiments showed these chiral di-imidazolium receptors exhibited excellent enantioselective recognition toward L- and D-amino acid derivatives in water or acetonitrile.
Keywords: UV-vis, enantioselective recognition, synthesis, molecular tweezers, Chiral imidazolium
Letters in Organic Chemistry
Title: Chiral Di-Imidazolium Molecular Tweezers: Synthesis and Enantioselective Recognition for Amino Acid Derivatives
Volume: 3 Issue: 5
Author(s): Jing-bo Lan, Ru-gang Xie, Sheng-jin Guo, Qin-xiang Xiang, Jin-song You, Kui Luo and He-yan Jiang
Affiliation:
Keywords: UV-vis, enantioselective recognition, synthesis, molecular tweezers, Chiral imidazolium
Abstract: A series of novel chiral di-imidazolium tweezers were synthesized from L-alanine and L-phenylalanine. These compounds featured two open arms and multipoint binding sites. UV spectroscopic titration experiments showed these chiral di-imidazolium receptors exhibited excellent enantioselective recognition toward L- and D-amino acid derivatives in water or acetonitrile.
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Cite this article as:
Lan Jing-bo, Xie Ru-gang, Guo Sheng-jin, Xiang Qin-xiang, You Jin-song, Luo Kui and Jiang He-yan, Chiral Di-Imidazolium Molecular Tweezers: Synthesis and Enantioselective Recognition for Amino Acid Derivatives, Letters in Organic Chemistry 2006; 3 (5) . https://dx.doi.org/10.2174/157017806776611854
DOI https://dx.doi.org/10.2174/157017806776611854 |
Print ISSN 1570-1786 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6255 |
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