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Current Microwave Chemistry

Editor-in-Chief

ISSN (Print): 2213-3356
ISSN (Online): 2213-3364

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Editorial

The Application of Microwaves in the Esterification of P-Acids

Author(s): György Keglevich*

Volume 9, Issue 2, 2022

Published on: 27 January, 2023

Page: [62 - 64] Pages: 3

DOI: 10.2174/2213335610666230105162405

Price: $65

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[1]
Keglevich G, Grün A, Bálint E, Kiss N Z, Jablonkai E. Microwave-assisted organophosphorus synthesis. Curr Org Chem 2013; 17(5): 545-54.
[http://dx.doi.org/10.2174/1385272811317050009]
[2]
Guénin E, Meziane D. Microwave assisted phosphorus organic chemistry: A review. Curr Org Chem 2011; 15(19): 3465-85.
[http://dx.doi.org/10.2174/138527211797374724]
[3]
Keglevich G, Kiss N Z, Mucsi Z, Körtvélyesi T. Insights into a surprising reaction: The microwave-assisted direct esterification of phosphinic acids. Org Biomol Chem 2012; 10(10): 2011-8.
[http://dx.doi.org/10.1039/c2ob06972e] [PMID: 22293944]
[4]
Quin L D. A Guide to Organophosphorus Chemistry. New York, US: Wiley 2000.
[5]
Kiss N Z, Keglevich G. Microwave-assisted direct esterification of cyclic phosphinic acids in the presence of ionic liquids. Tetrahedron Lett 2016; 57(9): 971-4.
[http://dx.doi.org/10.1016/j.tetlet.2016.01.044]
[6]
Kiss N Z, Keglevich G. Direct esterification of phosphinic and phosphonic acids enhanced by ionic liquid additives. Pure Appl Chem 2019; 91(1): 59-65.
[http://dx.doi.org/10.1515/pac-2018-1008]
[7]
Keglevich G, Kiss N Z, Grün A, Bálint E, Kovács T. Advantages of the microwave tool in organophosphorus syntheses. Synthesis 2017; 49(14): 3069-83.
[http://dx.doi.org/10.1055/s-0036-1589031]
[8]
Keglevich G, Mucsi Z. Interpretation of the rate enhancing effect of microwaves. In: Cravotto G, Carnaroglio D, Eds. Microwave Chemistry. Berlin: De Gruyter 2017; pp. 53-64.
[http://dx.doi.org/10.1515/9783110479935-004]
[9]
Keglevich G, Greiner I, Mucsi Z. An interpretation of the rate enhancing effect of microwaves – modelling the distribution and effect of local overheating – A case study. Curr Org Chem 2015; 19(14): 1436-40.
[http://dx.doi.org/10.2174/1385272819666150528004505]
[10]
Keglevich G, Kiss N Z, Mucsi Z. Milestones in microwave-assisted organophosphorus chemistry. Pure Appl Chem 2016; 88(10-11): 931-9.
[http://dx.doi.org/10.1515/pac-2016-0604]
[11]
Keglevich G, Grün A, Bálint E. Microwave irradiation and phase transfer catalysis in C-, O- and N-alkylation reactions. Curr Org Synth 2013; 10(5): 751-63.
[http://dx.doi.org/10.2174/1570179411310050006]
[12]
Bálint E, Jablonkai E, Bálint M, Keglevich G. Alkylating esterification of 1-hydroxy-3-phospholene oxides under solventless MW conditions. Heteroatom Chem 2010; 21(4)
[http://dx.doi.org/10.1002/hc.20596]
[13]
Keglevich G, Bálint E, Kiss N Z, et al. Microwave-assisted esterification of phosphinic acids. Curr Org Chem 2011; 15(11): 1802-10.
[http://dx.doi.org/10.2174/138527211795656570]
[14]
Henyecz R, Kiss A, Mórocz V, Kiss N Z, Keglevich G. Synthesis of phosphonates from phenylphosphonic acid and its monoesters. Synth Commun 2019; 49(20): 2642-50.
[http://dx.doi.org/10.1080/00397911.2019.1637894]
[15]
Harsági N, Henyecz R, Ábrányi-Balogh P, Drahos L, Keglevich G. Microwave-assisted ionic liquid-catalyzed selective monoesterification of alkylphosphonic acids – an experimental and a theoretical study. Molecules 2021; 26(17): 5303.
[http://dx.doi.org/10.3390/molecules26175303] [PMID: 34500735]
[16]
Harsági N, Kiss N Z, Keglevich G. P-Chloride-free synthesis of phosphoric esters: microwave-assisted esterification of alkyl- and dialkyl phosphoric ester-acids obtained from phosphorus pentoxide. Synthesis 2022; 54(13): 3047-54.
[http://dx.doi.org/10.1055/a-1811-8586]
[17]
Ábrányi-Balogh P, Harsági N, Drahos L, Keglevich G. A study on the direct esterification of monoalkylphosphates and dialkylphosphates; The conversion of the latter species to trialkylphosphates by alkylating esterification. Molecules 2022; 27(15): 4674.
[http://dx.doi.org/10.3390/molecules27154674] [PMID: 35897850]

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