Electrocatalytic Oxidation of Biomass-derived 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid Coupled with H2 Evolution

Title:Electrocatalytic Oxidation of Biomass-derived 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid Coupled with H2 Evolution

Volume: 25 Issue: 23

Author(s): Ye Meng and Hu Li*

Affiliation:

• State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering, Key Laboratory of Green Pesticide & Agricultural Bioengineering, Ministry of Education, State-Local Joint Laboratory for Comprehensive Utilization of Biomass, Center for R&D of Fine Chemicals, Guizhou University, Guiyang, Guizhou 550025,China

Keywords: Biomass valorization, electrocatalyst, redox mediators, bifunctional electrocatalysts, 5-hydroxymethylfurfural, 2, 5-furandicarboxylic acid, hydrogen evolution.

Abstract: Simultaneous electrocatalytic conversion of biomass into high-value products and electrolysis of water for hydrogen are promising strategies to relieve the fossil energy crisis. Herein, we overview the recent advances and perspectives in the electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF) and water reduction to synchronously produce value-added 2,5-furandicarboxylic acid (FDCA) and hydrogen fuel. Two strategies of bifunctional electrocatalysts and redox mediators are discussed. Oxidation of HME to FDCA was found to be more thermodynamically and kinetically favorable than the Oxygen Evolution Reaction (OER). Moreover, the opportunities and challenges brought by them are presented.

Cite this article as:

Meng Ye and Li Hu *, Electrocatalytic Oxidation of Biomass-derived 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid Coupled with H2 Evolution, Current Organic Chemistry 2021; 25 (23) . https://dx.doi.org/10.2174/1385272825666210927101643