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Current Organic Chemistry

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ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

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Review Article

Formation of Carbon-Nitrogen Bond Mediated by Hypervalent Iodine Reagents Under Metal-free Conditions

Author(s): Yaxin O. Yang, Xi Wang, Jiaxi Xiao, Yadong Li, Fengxia Sun* and Yunfei Du*

Volume 25, Issue 1, 2021

Published on: 17 November, 2020

Page: [68 - 132] Pages: 65

DOI: 10.2174/1385272822999201117154919

Price: $65

Abstract

In the past several decades, hypervalent iodine chemistry has witnessed prosperous development as hypervalent iodine reagents have been widely used in various organic transformations. Specifically, hypervalent iodine reagents have been vastly used in various bondforming reactions. Among these oxidative coupling reactions, the reactions involving the formation of C-N bond have been extensively explored to construct various heterocyclic skeletons and synthesize various useful building blocks. This review article is to summarize all the transformations in which carbon-nitrogen bond formation occurred by using hypervalent iodine reagents under metal-free conditions.

Keywords: Hypervalent iodine reagent, oxidative coupling, C-N bond formation, oxidation, metal-free conditions, rearrangement.

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Graphical Abstract

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