Abstract
This review covers literature on enantioselective synthesis of molecules with substituted quaternary carbon stereocenters from 1992 to 2002. In this overview, we will consider not only the construction of stereocenter itself by generation of carbon-carbon bond or heteroatom-carbon bond, but also other approachs which deal with the preparation of chiral compounds having this type of stereocenters, such as resolution or enantioselective desymmetrization.
Keywords: Enantioselective, Oxygen-, Nitrogen- and Halogen, stereocenters, chiral compounds, desymmetrization
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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