Abstract
α-Halo ethers used in the protection of alcohols for the years 2012 - 2014 have been reviewed. The conditions for formation and cleavage of protected alcohols are presented in tables. The α-halo ethers that have been reviewed are: benzyloxymethyl chloride (BOMCl), ethoxymethyl chloride (EOMCl), 2-methoxyethoxymethyl chloride (MEMCl), methoxymethyl bromide (MOMBr), methoxymethyl chloride (MOMCl) and 2-(trimethylsilyl)ethoxymethyl chloride (SEMCl).
Keywords: Acetals, protecting reagents, protection of alcohols, α-Halo ethers.
Graphical Abstract
Mini-Reviews in Organic Chemistry
Title:The Use of α-Halo Ethers in the Protection of Alcohols. Years 2012 - 2014
Volume: 12 Issue: 4
Author(s): Tore Benneche
Affiliation:
Keywords: Acetals, protecting reagents, protection of alcohols, α-Halo ethers.
Abstract: α-Halo ethers used in the protection of alcohols for the years 2012 - 2014 have been reviewed. The conditions for formation and cleavage of protected alcohols are presented in tables. The α-halo ethers that have been reviewed are: benzyloxymethyl chloride (BOMCl), ethoxymethyl chloride (EOMCl), 2-methoxyethoxymethyl chloride (MEMCl), methoxymethyl bromide (MOMBr), methoxymethyl chloride (MOMCl) and 2-(trimethylsilyl)ethoxymethyl chloride (SEMCl).
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Cite this article as:
Benneche Tore, The Use of α-Halo Ethers in the Protection of Alcohols. Years 2012 - 2014, Mini-Reviews in Organic Chemistry 2015; 12 (4) . https://dx.doi.org/10.2174/1570193X12666150930222755
DOI https://dx.doi.org/10.2174/1570193X12666150930222755 |
Print ISSN 1570-193X |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6298 |
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