Abstract
Herein, poly(ethylene glycol) and azobenzene are used as thermo- and photo-sensitive unit, respectively; and azobenzene, heptamethylene, and adamantyl are utilized as photo-responsive recognition group, second recognition group, and stopper for α-cyclodextrin to construct a novel dually thermo- and photo-responsive supramolecular system whose phase transition can be regulated by the photo-controlled selective molecular recognition of α-cyclodextrin.
Keywords: Cyclodextrin, inclusion complex, molecular recognition, stimuli responsive, supramolecular system.
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Current Organic Chemistry
Title:Phase Transition Regulated by Photo-Controlled Molecular Recognition of Alpha- Cyclodextrin
Volume: 19 Issue: 3
Author(s): Jie Hu, Rong Zhao, Di Wang, Xinglong Xu, Xiaoping Chen and Dan Shen
Affiliation:
Keywords: Cyclodextrin, inclusion complex, molecular recognition, stimuli responsive, supramolecular system.
Abstract: Herein, poly(ethylene glycol) and azobenzene are used as thermo- and photo-sensitive unit, respectively; and azobenzene, heptamethylene, and adamantyl are utilized as photo-responsive recognition group, second recognition group, and stopper for α-cyclodextrin to construct a novel dually thermo- and photo-responsive supramolecular system whose phase transition can be regulated by the photo-controlled selective molecular recognition of α-cyclodextrin.
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Cite this article as:
Hu Jie, Zhao Rong, Wang Di, Xu Xinglong, Chen Xiaoping and Shen Dan, Phase Transition Regulated by Photo-Controlled Molecular Recognition of Alpha- Cyclodextrin, Current Organic Chemistry 2015; 19 (3) . https://dx.doi.org/10.2174/1385272819666150120233927
DOI https://dx.doi.org/10.2174/1385272819666150120233927 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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