Photorelease Study of γ- Amino Glutamate from 1,2,2-triphenyl-ethanone

Sukjin      Jang; Azhad      Chowdhury; Jeonghee      Kang; Jong   I.   Lee

doi:10.2174/15701786113106660089

Abstract

A phototrigger, 1,2,2-triphenylethanone (TPE), was synthesized for the photorelease study. The photorelease of 1,2,2-triphenylethanonyl N-t-Boc-γ-amino glutamate (TPE- N-t-Boc-GABA) showed the quantum efficiency of Φ = 0.75. The phototrigger underwent further transformations that yielded Benzo[b]phenanthro[9,10-d]furan (9).

Keywords: Photorelease, phototrigger, photoremovable protecting group, GABA.

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Letters in Organic Chemistry

Title:Photorelease Study of γ- Amino Glutamate from 1,2,2-triphenyl-ethanone

Volume: 11 Issue: 3

Author(s): Sukjin Jang, Azhad Chowdhury, Jeonghee Kang and Jong I. Lee

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Keywords: Photorelease, phototrigger, photoremovable protecting group, GABA.

Abstract: A phototrigger, 1,2,2-triphenylethanone (TPE), was synthesized for the photorelease study. The photorelease of 1,2,2-triphenylethanonyl N-t-Boc-γ-amino glutamate (TPE- N-t-Boc-GABA) showed the quantum efficiency of Φ = 0.75. The phototrigger underwent further transformations that yielded Benzo[b]phenanthro[9,10-d]furan (9).

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Jang Sukjin, Chowdhury Azhad, Kang Jeonghee and Lee I. Jong, Photorelease Study of γ- Amino Glutamate from 1,2,2-triphenyl-ethanone, Letters in Organic Chemistry 2014; 11 (3) . https://dx.doi.org/10.2174/15701786113106660089