Abstract
The scope of organometallic reactions on solid phase has lately expanded to include many new reactions. In this review, we summarise the recent developments in this area, covering reactions such as metathesis, carbene insertion, radical-mediated transformations, the use of organomagnesium, organozinc and organocopper reagents, applications of titanium alkylidenes for alkene synthesis, as well as the Pauson-Khand reaction, hydroformylation and other methods using metal carbonyl reagents. Palladium-catalysed reactions are not included as this area has been recently reviewed (vide infra).
Keywords: combinatorial chemistry, organometallic reactions, metathesis, carbonyl reagents, carbon-carbon bond formation, grignard reaction, hydroxylamines
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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