Abstract
The synthesis of some novel (spirocycloalkenyl)trimethylsilylacetylenes employing the Sonogashira coupling reaction of the corresponding novel spirocycloalkenyliodides with trimethylsilylacetylene and Pd(PPh3)2Cl2/CuI catalyst in yields ranging 79-84% is reported. The compounds would serve as novel (spirocycloalkenyl)acetylenic anionic synthons.
Keywords: Acetylenic anionic synthons, enynes, silylacetylenes, spirocycloalkenes, Sonogashira coupling.
Letters in Organic Chemistry
Title:Palladium Catalyzed Synthesis of Some Novel (Spirocycloalkenyl) Trimethylsilylacetylenes
Volume: 10 Issue: 6
Author(s): Manjunatha Achanna Venkatesha and HariPrasad Suresh
Affiliation:
Keywords: Acetylenic anionic synthons, enynes, silylacetylenes, spirocycloalkenes, Sonogashira coupling.
Abstract: The synthesis of some novel (spirocycloalkenyl)trimethylsilylacetylenes employing the Sonogashira coupling reaction of the corresponding novel spirocycloalkenyliodides with trimethylsilylacetylene and Pd(PPh3)2Cl2/CuI catalyst in yields ranging 79-84% is reported. The compounds would serve as novel (spirocycloalkenyl)acetylenic anionic synthons.
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Cite this article as:
Venkatesha Achanna Manjunatha and Suresh HariPrasad, Palladium Catalyzed Synthesis of Some Novel (Spirocycloalkenyl) Trimethylsilylacetylenes, Letters in Organic Chemistry 2013; 10 (6) . https://dx.doi.org/10.2174/15701786113109990007
DOI https://dx.doi.org/10.2174/15701786113109990007 |
Print ISSN 1570-1786 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6255 |
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