Abstract
A series of mono- and bis-benzimidazolium and imidazolium salts of 4-pyrone derivatives has been synthesized in good yields, by various quaternization reactions of halomethyl derivatives of 4H-pyran-4-ones. These salts can be used as novel precursors of functionalized N-heterocyclic carbenes and some of them as novel ionic liquids.
Keywords: 4-pyrones, benzimidazolium salts, imidazolium salts, KI, kojic acid, substitution reactions, ionic, thermal stability, transformations, synthetic
Letters in Organic Chemistry
Title:Synthesis of Novel Imidazolium and Benzimidazolium Salts from Halomethyl Derivatives of 4-Pyrones
Volume: 9 Issue: 9
Author(s): Zarrin Ghasemi, Mahdi Gholamhoseini-Nazari, Maryam Allahvirdinesbat, Mahnaz Saraei and Aziz Shahrisa
Affiliation:
Keywords: 4-pyrones, benzimidazolium salts, imidazolium salts, KI, kojic acid, substitution reactions, ionic, thermal stability, transformations, synthetic
Abstract: A series of mono- and bis-benzimidazolium and imidazolium salts of 4-pyrone derivatives has been synthesized in good yields, by various quaternization reactions of halomethyl derivatives of 4H-pyran-4-ones. These salts can be used as novel precursors of functionalized N-heterocyclic carbenes and some of them as novel ionic liquids.
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Cite this article as:
Ghasemi Zarrin, Gholamhoseini-Nazari Mahdi, Allahvirdinesbat Maryam, Saraei Mahnaz and Shahrisa Aziz, Synthesis of Novel Imidazolium and Benzimidazolium Salts from Halomethyl Derivatives of 4-Pyrones, Letters in Organic Chemistry 2012; 9 (9) . https://dx.doi.org/10.2174/157017812803521153
DOI https://dx.doi.org/10.2174/157017812803521153 |
Print ISSN 1570-1786 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6255 |
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