Abstract
RuCl3·3H2O-catalyzed stereoselective transfer semihydrogenation of diarylacetylenes with HCOOH as hydrogen source affording trans-stilbenes in good to high yields is developed.
Keywords: Diarylacetylenes, formic acid, hydrogen transfer, ruthenium trichloride hydrate, semihydrogenation, trans-stilbene, stereodivergence, stereoselectivity, chemoselectivity, cis-stilbene, Mass spectra , substituents, chemical shifts, stereoisomers
Current Catalysis
Title:HCOOH/RuCl3·3H2O: An Efficient Hydrogen Transfer System for Highly Chemo- and Stereoselective Semihydrogenation of Diaryl Acetylenes Affording trans-Stilbenes
Volume: 1 Issue: 2
Author(s): Jie Li, Renqin Zeng and Ruimao Hua
Affiliation:
Keywords: Diarylacetylenes, formic acid, hydrogen transfer, ruthenium trichloride hydrate, semihydrogenation, trans-stilbene, stereodivergence, stereoselectivity, chemoselectivity, cis-stilbene, Mass spectra , substituents, chemical shifts, stereoisomers
Abstract: RuCl3·3H2O-catalyzed stereoselective transfer semihydrogenation of diarylacetylenes with HCOOH as hydrogen source affording trans-stilbenes in good to high yields is developed.
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Cite this article as:
Li Jie, Zeng Renqin and Hua Ruimao, HCOOH/RuCl3·3H2O: An Efficient Hydrogen Transfer System for Highly Chemo- and Stereoselective Semihydrogenation of Diaryl Acetylenes Affording trans-Stilbenes, Current Catalysis 2012; 1 (2) . https://dx.doi.org/10.2174/2211544711201020125
DOI https://dx.doi.org/10.2174/2211544711201020125 |
Print ISSN 2211-5447 |
Publisher Name Bentham Science Publisher |
Online ISSN 2211-5455 |
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