MgI2 Etherate-Catalyzed Three-Component Allylation: A Facile and Efficient Synthesis of Homoallylic Amines

Xingxian      Zhang; Saisai      Ye; Shenghui      Hu

doi:10.2174/157017811796064403

Abstract

MgI2 etherate-catalyzed three-component condensation of aldehydes, amines and allyltributylstannane under mild and neutral reaction conditions was developed and efficiently afforded the corresponding homoallylic amine derivatives in good to excellent yields.

Keywords: Aldehydes, allyltributylstannane, homoallylic amines, MgI2 etherate, organometallics, allylpalladiumcomplex, lanthanide, triflates, montmorillonite, Lewis acid

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Letters in Organic Chemistry

Title: MgI2 Etherate-Catalyzed Three-Component Allylation: A Facile and Efficient Synthesis of Homoallylic Amines

Volume: 8 Issue: 6

Author(s): Xingxian Zhang, Saisai Ye and Shenghui Hu

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Keywords: Aldehydes, allyltributylstannane, homoallylic amines, MgI2 etherate, organometallics, allylpalladiumcomplex, lanthanide, triflates, montmorillonite, Lewis acid

Abstract: MgI2 etherate-catalyzed three-component condensation of aldehydes, amines and allyltributylstannane under mild and neutral reaction conditions was developed and efficiently afforded the corresponding homoallylic amine derivatives in good to excellent yields.

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Zhang Xingxian, Ye Saisai and Hu Shenghui, MgI2 Etherate-Catalyzed Three-Component Allylation: A Facile and Efficient Synthesis of Homoallylic Amines, Letters in Organic Chemistry 2011; 8 (6) . https://dx.doi.org/10.2174/157017811796064403