An Approach to Synthesis of 3-Aryl-2-Oxazolidinones and In Situ`Click` Assembly of 1,2,3-Triazole Oxazolidinones

Xingxian      Zhang; Cheng      Li; Wei      Chen; Xiang      Wu

doi:10.2174/157017810791112414

Abstract

A facile and efficient addition of isocyanates with epoxides in the presence of MgI2 etherate was reported in good yields. The corresponding 2-oxazolidinone could be easily converted into 1,2,3-triazole-oxazolidinone by click reaction in excellent yield.

Keywords: Isocyanate, epoxide, oxazolidinone, MgI2 etherate, click reaction

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Letters in Organic Chemistry

Title: An Approach to Synthesis of 3-Aryl-2-Oxazolidinones and In Situ`Click` Assembly of 1,2,3-Triazole Oxazolidinones

Volume: 7 Issue: 3

Author(s): Xingxian Zhang, Cheng Li, Wei Chen and Xiang Wu

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Keywords: Isocyanate, epoxide, oxazolidinone, MgI2 etherate, click reaction

Abstract: A facile and efficient addition of isocyanates with epoxides in the presence of MgI2 etherate was reported in good yields. The corresponding 2-oxazolidinone could be easily converted into 1,2,3-triazole-oxazolidinone by click reaction in excellent yield.

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Zhang Xingxian, Li Cheng, Chen Wei and Wu Xiang, An Approach to Synthesis of 3-Aryl-2-Oxazolidinones and In Situ`Click` Assembly of 1,2,3-Triazole Oxazolidinones, Letters in Organic Chemistry 2010; 7 (3) . https://dx.doi.org/10.2174/157017810791112414