Reaction of Atomic Carbon with Isomeric Cresols (Supplementary Material)

Ilkay      Sokmen; Abdulilah      Ece; Bulent      Duz; Fatma      Sevin

doi:10.2174/157017809790442907

Abstract

Reaction of atomic carbon with isomeric cresols generates methyltropones and xylenols. Methyltropone to xylenol ratio was found to be highest for m-cresol and lowest for p-cresol. Stability of singlet carbenes produced after insertion of atomic carbon into C-H bonds of cresols plays an important role in the observed ratios.

Keywords: Carbon arc, carbene, methyltropone, xylenol

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Letters in Organic Chemistry

Title: Reaction of Atomic Carbon with Isomeric Cresols (Supplementary Material)

Volume: 6 Issue: 8

Author(s): Ilkay Sokmen, Abdulilah Ece, Bulent Duz and Fatma Sevin

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Keywords: Carbon arc, carbene, methyltropone, xylenol

Abstract: Reaction of atomic carbon with isomeric cresols generates methyltropones and xylenols. Methyltropone to xylenol ratio was found to be highest for m-cresol and lowest for p-cresol. Stability of singlet carbenes produced after insertion of atomic carbon into C-H bonds of cresols plays an important role in the observed ratios.

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Sokmen Ilkay, Ece Abdulilah, Duz Bulent and Sevin Fatma, Reaction of Atomic Carbon with Isomeric Cresols (Supplementary Material), Letters in Organic Chemistry 2009; 6 (8) . https://dx.doi.org/10.2174/157017809790442907