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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Asymmetric Synthesis of Chiral Organoselenium Compounds

Author(s): Chengjian Zhu and Yijun Huang

Volume 10, Issue 15, 2006

Page: [1905 - 1920] Pages: 16

DOI: 10.2174/138527206778521240

Price: $65

Abstract

Chiral organoselenium compounds can be attained from three types of asymmetric synthesis. Chiral substratecontrolled methods, chiral auxiliary-controlled methods, and chiral catalyst-controlled methods toward optically active organoselenium derivatives were illustrated. The strategy and classification of methods underlying all asymmetric synthesis therefore involve enantiomerically pure compounds to influence the stereochemical outcome of the reactions. In this review, the advances in asymmetric synthesis of some important classes of chiral organoselenium compounds were described.

Keywords: Prochiral Olefin, Selenocyclization, regioselectivity, ammonium persulfate, Seleno Alcohols


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