A Convenient Access to the Piperidine Ring by Cyclization of Allylsilyl Substituted N- cyliminium and Iminium Ions: Application to the Synthesis of Piperidine Alkaloids.

R.      Remuson; Y.      Gelas-Mialhe

doi:10.2174/157019308785161701

Abstract

This review relates a new access to the piperidine ring by intramolecular cyclization of acyl iminium and iminium ions substituted by an allylsilyl side chain as an internal Π-nucleophile. This methodology was applied to the synthesis of piperidine alkaloids

Keywords: Piperidine, iminium ions, N-acyliminium ions, indolizidine, quinolizidine

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Mini-Reviews in Organic Chemistry

Title: A Convenient Access to the Piperidine Ring by Cyclization of Allylsilyl Substituted N- cyliminium and Iminium Ions: Application to the Synthesis of Piperidine Alkaloids.

Volume: 5 Issue: 3

Author(s): R. Remuson and Y. Gelas-Mialhe

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Keywords: Piperidine, iminium ions, N-acyliminium ions, indolizidine, quinolizidine

Abstract: This review relates a new access to the piperidine ring by intramolecular cyclization of acyl iminium and iminium ions substituted by an allylsilyl side chain as an internal Π-nucleophile. This methodology was applied to the synthesis of piperidine alkaloids

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Remuson R. and Gelas-Mialhe Y., A Convenient Access to the Piperidine Ring by Cyclization of Allylsilyl Substituted N- cyliminium and Iminium Ions: Application to the Synthesis of Piperidine Alkaloids., Mini-Reviews in Organic Chemistry 2008; 5 (3) . https://dx.doi.org/10.2174/157019308785161701