Rhodium-Catalyzed Hydroformylation Promoted by Modified Cyclodextrins:Current Scope and Future Developments

Frederic      Hapiot; Loic      Leclercq; Nathalie      Azaroual; Sophie      Fourmentin; Sebastien      Tilloy; Eric      Monflier

doi:10.2174/157017908784221585

Abstract

The contribution of modified cyclodextrins in aqueous biphasic rhodium-catalyzed hydroformylation of higher olefins is tackled, taking into account previous results and new experimental data. The role of the cyclodextrins is emphasized and discussed through the analysis of numerous parameters. Development outlooks are also presented.

Keywords: Hydroformylation, cyclodextrin, rhodium, aqueous catalysis, interface

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Current Organic Synthesis

Title: Rhodium-Catalyzed Hydroformylation Promoted by Modified Cyclodextrins:Current Scope and Future Developments

Volume: 5 Issue: 2

Author(s): Frederic Hapiot, Loic Leclercq, Nathalie Azaroual, Sophie Fourmentin, Sebastien Tilloy and Eric Monflier

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Keywords: Hydroformylation, cyclodextrin, rhodium, aqueous catalysis, interface

Abstract: The contribution of modified cyclodextrins in aqueous biphasic rhodium-catalyzed hydroformylation of higher olefins is tackled, taking into account previous results and new experimental data. The role of the cyclodextrins is emphasized and discussed through the analysis of numerous parameters. Development outlooks are also presented.

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Hapiot Frederic, Leclercq Loic, Azaroual Nathalie, Fourmentin Sophie, Tilloy Sebastien and Monflier Eric, Rhodium-Catalyzed Hydroformylation Promoted by Modified Cyclodextrins:Current Scope and Future Developments, Current Organic Synthesis 2008; 5 (2) . https://dx.doi.org/10.2174/157017908784221585