New Efficient Method for the Preparation of 2-Aryl-4,6-Dinitroindoles: Reductive Cyclization of E-1-(2-Azido-4,6-Dinitrophenyl)-2-Arylethenes

Vasily   V.   Mezhnev; Mikhail   D.   Dutov; Svyatoslav   A.   Shevelev

doi:10.2174/157017808783955907

Abstract

A new efficient method for the preparation of 2-aryl-4,6-dinitroindoles based on reductive cyclization of E-2- azido-4,6-dinitrostilbenes under the action of FeCl3 6H2O – NaI system – in the CH3CN media at room temperature has been developed.

Keywords: 4,6-dinitroindoles, E-1-(2-azido-4,6-dinitrophenyl)-2-arylethenes, reductive cyclization

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Letters in Organic Chemistry

Title: New Efficient Method for the Preparation of 2-Aryl-4,6-Dinitroindoles: Reductive Cyclization of E-1-(2-Azido-4,6-Dinitrophenyl)-2-Arylethenes

Volume: 5 Issue: 3

Author(s): Vasily V. Mezhnev, Mikhail D. Dutov and Svyatoslav A. Shevelev

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Keywords: 4,6-dinitroindoles, E-1-(2-azido-4,6-dinitrophenyl)-2-arylethenes, reductive cyclization

Abstract: A new efficient method for the preparation of 2-aryl-4,6-dinitroindoles based on reductive cyclization of E-2- azido-4,6-dinitrostilbenes under the action of FeCl3 6H2O – NaI system – in the CH3CN media at room temperature has been developed.

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Mezhnev V. Vasily, Dutov D. Mikhail and Shevelev A. Svyatoslav, New Efficient Method for the Preparation of 2-Aryl-4,6-Dinitroindoles: Reductive Cyclization of E-1-(2-Azido-4,6-Dinitrophenyl)-2-Arylethenes, Letters in Organic Chemistry 2008; 5 (3) . https://dx.doi.org/10.2174/157017808783955907